“…5 Keggin, 6,7 Wells-Dawson, 8 Anderson-Evans 9 and Lindqvist 10 POMs are forms of intensely investigated POM archetypes instantiated by thousands of POM formulations and have a profound technological impact in catalysis, 11,12 life-science 13,14 and variety of energy storage [15][16][17] and energy conversion "POMtronics". [18][19][20] As POMs constitute the most complex inorganic materials, 21 a signicant portion of their development relied on probabilistic synthetic self-assembly approaches. 22 Therefore, a signicant challenge in the history of POM chemistry was to decipher the relationship between archetypes and how they are interconnected.…”