2024
DOI: 10.1002/smll.202408634
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Molecular Propeller Tethering on a Dipeptide Induces a One‐Step Conversion of Its Secondary Structure on Water Surface Promoted by Chiral Supramolecular Assembly

Sandip Biswas,
Umesh,
Bidisa Das
et al.

Abstract: Water provides a unique surface for the formation of directed self‐assembly and transformation of secondary structures of peptides and proteins as witnessed in the biological systems. Herein a one‐step transformation of an amyloid‐derived dipeptide is reported from β‐sheet to α‐helix structures on the water surface, facilitated by chiral supramolecular assembly. The study utilizes various analytical techniques to elucidate the structural transformation and the supramolecular packing of the peptide assemblies. … Show more

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