Molecularly imprinted polymer thin films on quartz crystal microbalance using a surface bound photo-radical initiator

Piacham, Theeraphon; Josell, Åsa; Arwin, Hans; Prachayasittikul, Virapong; Ye, Lei

doi:10.1016/j.aca.2004.12.067

Cited by 70 publications

(45 citation statements)

References 15 publications

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“…Although for different applications it is possible to design and synthsize specialized MIPs for their intended use [60][61][62][63], it is in practice very inconvenient because the reaction conditions for MIP synthesis, for example, the use of high temperature, organic solvents, and protection gas, cannot be fulfilled. To solve this problem, one feasible approach is to develop MIPs as modular building blocks that can be handled like antibodies for different applications.…”

Section: Mips As Building Blocks For Multifunctional Materialsmentioning

confidence: 99%

Synthetic Strategies in Molecular Imprinting

2015

Molecularly Imprinted Polymers in Biotechnology

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This chapter introduces the basic principle and the synthetic aspects of molecular imprinting. First, the use of a molecular template to guide the location of functional groups inside molecularly imprinted cavities is explained. Three different mechanisms that ensure a molecular template associates with functional monomers or the imprinted polymers, that is, through reversible covalent, noncovalent, and sacrificial covalent bonds, are then described. The main focus is put on noncovalent molecular imprinting using free radical polymerization. The merits of using classical radical polymerization and more sophisticated, controlled radical polymerization are analyzed. After these synthetic chemistry aspects, the chapter continues to discuss the different polymerization processes that can be used to prepare well-defined polymer monoliths, microspheres, and nanoparticles. New top-down processing techniques that produce micro- and nanopatterns of imprinted polymers are also reviewed. The chapter finishes with a brief introduction to using imprinted polymers as building blocks to construct new functional materials and devices, which we consider as one important direction for further development.

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Section: Mips As Building Blocks For Multifunctional Materialsmentioning

confidence: 99%

Synthetic Strategies in Molecular Imprinting

2015

Molecularly Imprinted Polymers in Biotechnology

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“…Piacham et al [86] prepare ultra-thin MIP films using surface initiated radical polymerization. Polymer films are directly formed on gold-coated quartz crystal resonator, which offers easy monitoring of polymer growth.…”

Section: Surface Imprinting Polymerizationmentioning

confidence: 99%

Characteristic and Synthetic Approach of Molecularly Imprinted Polymer

Yan

Row

2006

IJMS

462

231

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Abstract:Molecularly imprinted polymers (MIP) exhibiting high selectivity and affinity to the predetermined molecule (template) are now seeing a fast growing research. However, optimization of the imprinted products is difficult due to the fact that there are many variables to consider, some or all of which can potentially impact upon the chemical, morphological and molecular recognition properties of the imprinted materials. This review present a summary of the principal synthetic considerations pertaining to good practice in the polymerization aspects of molecular imprinting, and is primarily aimed at researcher familiar with molecular imprinting methods but with little or no prior experience in polymer synthesis. The synthesis, characteristic, effect of molecular recognition and different preparation methods of MIP in recent few years are discussed in this review, unsolved problems and possible developments of MIP were also been briefly discussed.

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“…Other small molecule detection assays exploiting MIPs as the recognition element include those for terpenes (Percival et al, 2001), aminopyrene (Tan et al, 2001a) and propranolol (Piacham et al, 2005).…”

Section: Molecularly Imprinted Polymersmentioning

confidence: 99%

A survey of the 2001 to 2005 quartz crystal microbalance biosensor literature: applications of acoustic physics to the analysis of biomolecular interactions

Cooper¹,

Singleton²

2007

J of Molecular Recognition

336

205

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The widespread exploitation of biosensors in the analysis of molecular recognition has its origins in the mid-1990s following the release of commercial systems based on surface plasmon resonance (SPR). More recently, platforms based on piezoelectric acoustic sensors (principally 'bulk acoustic wave' (BAW), 'thickness shear mode' (TSM) sensors or 'quartz crystal microbalances' (QCM)), have been released that are driving the publication of a large number of papers analysing binding specificities, affinities, kinetics and conformational changes associated with a molecular recognition event. This article highlights salient theoretical and practical aspects of the technologies that underpin acoustic analysis, then reviews exemplary papers in key application areas involving small molecular weight ligands, carbohydrates, proteins, nucleic acids, viruses, bacteria, cells and lipidic and polymeric interfaces. Key differentiators between optical and acoustic sensing modalities are also reviewed.

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Molecularly imprinted polymer thin films on quartz crystal microbalance using a surface bound photo-radical initiator

Cited by 70 publications

References 15 publications

Synthetic Strategies in Molecular Imprinting

Synthetic Strategies in Molecular Imprinting

Characteristic and Synthetic Approach of Molecularly Imprinted Polymer

A survey of the 2001 to 2005 quartz crystal microbalance biosensor literature: applications of acoustic physics to the analysis of biomolecular interactions

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