Monitoring CO ₂ , CO and CH ₄ , affected or not by ventilation and anthropogenic activities, in the galleries of the Underground Research Laboratory (URL) of Meuse/Haute-Marne

Abstract

The alternation between periods of ventilation and non-ventilation of the galleries in the Meuse/Haute-Marne Underground Research Laboratory (URL) within the Callovo-Oxfordian argillaceous rock affects the content of CO 2 , CO and CH 4 in atmospheric air. Monitoring the evolution of the gas composition in the galleries was conducted over a period of about 4 months. Two models of infrared laser spectroscope (Picarro) were used, one to measure CO 2 , CO, and CH 4 concentrations and the other to measure CH 4 isotopic compositions. The results show a night/day periodicity with the highest concentrations at nighttime and the lowest during the daytime in the URL. Long-term monitoring of these gases at the surface shows the same evolution, but with different amplitudes. Moreover, in the URL, a weekday, weekend/holiday periodicity superimposed. The concentrations of CO 2 in the galleries are influenced by human activities and ventilation. During working days, the galleries are ventilated, and human activities increase the CO 2 concentrations. Conversely, during weekends and holidays, CO 2 concentrations decrease due to the cessation of ventilation and human activities, and consumption of CO 2 by concrete carbonation. The data analysis confirms CH 4 source coming from the rock and reveals compelling evidence of CO sources that are likely originating from rock and/or gallery engineered structure materials. Despite the difficulties in quantifying local sources and sinks of these gases, this study demonstrates the feasibility of obtaining valuable insights into their variability. This study provides information on potential sources and sinks of CO 2 , CO, and CH 4 in this context.