Monoacrylated cyclodextrin via “click” reaction and copolymerization with N-isopropylacrylamide: guest controlled solution properties

Chiral recognition of ephedrine: Hydrophilic polymers bearing β-cyclodextrin moieties as chiral sensitive host molecules

“…As reported recently, the CD containing NIPAAm copolymer 1 exhibits lower critical solution temperature (LCST) behavior in water [23]. As expected, the supramolecular system 2 turned out to be soluble in cold water only below the LCST of 32 °C.…”

Switching the Solubility of PMMA Bearing Attached Cyclodextrin‐Moieties by Supramolecular Interactions with Ionic Liquids

“…[13] The triazole-containing CD monomer 2 and MMA (4) were radically copolymerized in DMF-d 7 at different molar ratios using AIBN as the initiator to result in copolymers 3a to 3c (Scheme 1). The CD-methacrylate (2)/MMA molar ratios in the obtained copolymers are 1: 3, 1: 5, and 1: 10, respectively.…”

“…The triazol-CD monomer was prepared according to a method described previously. [13] IR spectra were recorded with a Nicolet 5 SXB FT-IR Spectrometer, equipped with an ATR unit. NMR spectra were recorded with a Bruker AC 500 at 20 8C.…”

Nanochain and vesicles formed by inclusion complexation of 4,4′-diaminobenzanilide with cyclodextrins

“…FTIR spectra were measured between wave numbers of 4000 and 400 cm ¡1 on Nicolet Avatar 360 FTIR spectrometer by using KBr to make pellets. 1 H NMR spectra were recorded on a Bruker AVANCE 400 MHz spectrometer using DMSO-d 6 (99.9%) as a solvent. Differential scanning calorimeter (DSC) data were recorded using Mettler Toledo DSC1 fitted with STR e software.…”

“…[3] CDs can form different aggregates under different conditions. Many new supramolecular assemblies have been planned, such as supramolecular gels, [4] supramolecular polymers, [5,6] rotaxanes, [7] nanospheres, [8] and vesicles based on CD inclusion complexes. The vesicles prepared by CD inclusion complexes have gained much attention due to their importance in enthusiastic natural biomembranes, [9,10] developing new biotechniques, smart materials, etc.…”