Monolithic two-terminal tandem solar cells using Sb2S3 and solution-processed PbS quantum dots achieving an open-circuit potential beyond 1.1 V

Abstract

Multijunction solar cells show the prospect to raise the theoretical efficiency limit of single junction solar cells by minimizing transmissive losses of large bandgap and emissive losses of lower bandgap absorber solar cells. In solar cell applications, Sb2S3 is considered an attractive absorber due to its elemental abundance, stability, and high absorption coefficient in the visible range of the solar spectrum, yet with a band gap of 1.7 eV it is transmissive for near-IR and IR photons. Using it as the top cell inside a tandem solar architecture in combination with a bottom cell employing e.g., PbS quantum dots, which have an adjustable band gap suitable for absorbing longer wavelengths, is hence a promising approach to harvest the solar spectrum more effectively. In this work, these two subcells are monolithically grown and connected in series by a poly(3,4-ethylene-dioxythiophene) polystyrene sulfonate (PEDOT:PSS)−ZnO tunnel junction as the recombination layer. We explore the surface morphology of ZnO QDs resulting from different spin coating conditions, which serve as the bottom cell’s electron transport material. Furthermore, we examine the differences in photogenerated current upon varying the PbS QDs absorber layer thickness and the electrical and optical characteristics of the tandem with respect to the standalone reference cells. This tandem architecture demonstrates an extended spectral absorption into the IR with an open-circuit potential exceeding 1.1 V and a power conversion efficiency of 5.6%, projecting above the PCE of each single-junction cell.

Colloidal quantum dot materials for next-generation near-infrared optoelectronics

“…Kim et al combined QDSC with the organic solar cell, resulting in a 2T organic/PbS CQD tandem solar cell with a PCE of 13.7%. 59 Crisp et al 60 and Kern et al 61 have developed CdTe/PbS CQD and Sb 2 S 3 /PbS CQD tandem solar cells and the PCE values of their devices have reached 4.7% and 5.64%, respectively. The PCE of the 2T Sb 2 S 3 /PbS CQD tandem solar cell presented by Kern et al has surpassed those of the control devices (Sb 2 S 3 and PbS CQD single junction devices).…”