Monomer-controlled self-switchable polymerization: a metal-free strategy for synthesizing multiblock copolymers from epoxides, <i>O</i>-phthalaldehyde, and CO<sub>2</sub>

Zhang, Qi; Niu, Mingxin; Zhang, Haotian; Hu, Chenyang; Pang, Xuan

doi:10.1039/d3py01035j

Polym. Chem.

2023

DOI: 10.1039/d3py01035j

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Monomer-controlled self-switchable polymerization: a metal-free strategy for synthesizing multiblock copolymers from epoxides, O-phthalaldehyde, and CO₂

Qi Zhang,

Mingxin Niu,

Haotian Zhang

et al.

Abstract: Advances in chemoselective ring-opening polymerization have enabled the preparation of copolymers with precisely controlled chain structure. However, the building blocks for the sequence-controlled polymers are mostly limited to polyether, polycarbonate...

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2024

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Recent progress of heterocycle ring‐opening (co)polymerization for the synthesis of sequence‐controlled block polyesters and polycarbonates

Zhao,

Hu,

Pang

et al. 2024

Smart Molecules

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Aliphatic polyesters and polycarbonates are among the promising sustainable polymers, which exhibit unique degradability and chain‐chain interactions owing to their heterofunctionality. However, monocomponent aliphatic polyesters and polycarbonates usually suffer from inferior properties and functionalities. By contrast, precisely modulated block copolymers composed of polyesters and polycarbonates give rise to sustainable materials with tailored performance. An efficient approach to synthesize the block copolymers is the ring‐opening (co)polymerization of the heterocycle monomers. Herein, this review presents the heterocycle monomer ring‐opening (co)polymerization for the formation of sequence‐controlled block polyesters and polycarbonates. Available synthetic strategies, different monomers, monomer combinations and the catalyst systems for the formation of different block polyesters and polycarbonates are summarized.

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Recent progress of heterocycle ring‐opening (co)polymerization for the synthesis of sequence‐controlled block polyesters and polycarbonates

Zhao,

Hu,

Pang

et al. 2024

Smart Molecules

View full text Add to dashboard Cite

show abstract

Low molar mass polycarbonate diols from degradation of terpolymers obtained by epoxide/o-phthalaldehyde/CO2 copolymerization

Patil,

Gnanou,

Feng

2024

Journal of CO2 Utilization

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Monomer-controlled self-switchable polymerization: a metal-free strategy for synthesizing multiblock copolymers from epoxides, O-phthalaldehyde, and CO₂

Abstract: Advances in chemoselective ring-opening polymerization have enabled the preparation of copolymers with precisely controlled chain structure. However, the building blocks for the sequence-controlled polymers are mostly limited to polyether, polycarbonate...

Cited by 2 publications

References 45 publications

Recent progress of heterocycle ring‐opening (co)polymerization for the synthesis of sequence‐controlled block polyesters and polycarbonates

Recent progress of heterocycle ring‐opening (co)polymerization for the synthesis of sequence‐controlled block polyesters and polycarbonates

Low molar mass polycarbonate diols from degradation of terpolymers obtained by epoxide/o-phthalaldehyde/CO2 copolymerization

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Monomer-controlled self-switchable polymerization: a metal-free strategy for synthesizing multiblock copolymers from epoxides, O-phthalaldehyde, and CO2

Abstract: Advances in chemoselective ring-opening polymerization have enabled the preparation of copolymers with precisely controlled chain structure. However, the building blocks for the sequence-controlled polymers are mostly limited to polyether, polycarbonate...

Cited by 2 publications

References 45 publications

Recent progress of heterocycle ring‐opening (co)polymerization for the synthesis of sequence‐controlled block polyesters and polycarbonates

Recent progress of heterocycle ring‐opening (co)polymerization for the synthesis of sequence‐controlled block polyesters and polycarbonates

Low molar mass polycarbonate diols from degradation of terpolymers obtained by epoxide/o-phthalaldehyde/CO2 copolymerization

Contact Info

Product

Resources

About

Monomer-controlled self-switchable polymerization: a metal-free strategy for synthesizing multiblock copolymers from epoxides, O-phthalaldehyde, and CO₂