Morpholinium chloroindate(iii) complex: a rare acentric structural arrangement leading to piezoelectric properties

Abstract

In(iii)-Based morpholinium complex, [C4H10NO]+[InCl5(C4H10NO)]−: crystal structure, origin of the structure polarity, and evidence of piezoelectric properties.

Towards ferroelectricity-inducing chains of halogenoantimonates(iii) and halogenobismuthates(iii)

“…S5 †) arising from the resonant piezoelectric contribution. 46,52,53 The asymmetric parts of the unit cells consist of one SbX 5 2À square pyramidal unit and two nonequivalent 2Aprm + cations, marked as A and B in Fig. 4a and b, forming dimers via N-H/N hydrogen bonds of $3 A in distance and angle 172 -175 .…”