This paper investigates the structure of the continuous liquid jet of a coaxial air-blast atomiser over a range of Weber numbers 60-1040, Reynolds numbers of liquid jet 5400-21700 and air to liquid momentum ratios of the two streams of 1.7-335. A novel optical technique, based on internal illumination of the liquid jet through the jet nozzle by a laser pulse, which excites a fluorescing dye introduced in the atomizing liquid, was used to obtain instantaneous measurements of the breakup length and the three dimensional location of the liquid core of the continuous liquid jet. The latter was achieved by simultaneously imaging the liquid jet from two directions normal to each other. Such measurements are usually prevented by droplets surrounding the liquid jet at the dense spray near the nozzle exit. The measurements showed that the break-up length of the liquid jet scaled well with the air to liquid momentum ratio. The standard deviation of the temporal fluctuations of the break-up length was around 10% of the mean breakup length for each considered flow condition. The instantaneous jet surface does not develop axi-symmetric wave structures but the time-averaged liquid jet is axi-symmetric around the nozzle axis, while the maximum deflection of the liquid jet occurs close to the breaking point.