Morphological, mechanical and rheological properties of poly(acrylonitrile-butadienestyrene)/polycarbonate/poly(ε-caprolactone) ternary blends

Hong, Jeong Hee; Song, Ki Heon; Lee, Hyung Gon; Han, Mi Sun; Kim, Youn Hee; Kim, Woo Nyon

doi:10.1007/bf03218825

Cited by 14 publications

(5 citation statements)

References 34 publications

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“…It also observed that the complex viscosity of the PP/ABS (70/30) blends changes more significant at the low‐frequency region. The complex viscosity at low‐frequency region is related to the interfacial properties of the polymer blends . In this study, it is may be due to the interfacial adhesion of PP/ABS blends was improved by adding PP‐ g ‐cardanol leading to a longer time relaxation.…”

Section: Resultsmentioning

confidence: 78%

Compatibilization of polypropylene/Poly(acrylonitrile‐butadiene‐styrene) blends by polypropylene‐graft‐cardanol

Deng

Mao

Lin

et al. 2014

J of Applied Polymer Sci

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The polypropylene-graft-cardanol (PP-g-cardanol) was prepared by reactive extrusion with polypropylene (PP) and natural renewable cardanol which could increase the interfacial energy of PP and inhibit the degradation of PP during the process of reactive extrusion and usage. In this article, PP-g-cardanol and polypropylene-graft-maleic anhydride (PP-g-MAH) were used as compatibilizers of the polypropylene (PP)/poly(acrylonitrile-butadiene-styrene) (ABS) blends. PP/ABS (70/30, wt %) blends with PP-g-cardanol and PP-g-MAH were prepared by a corotating twin-screw extruder. From the results of morphological studies, the droplet size of ABS was minimized to 1.93 and 2.01 lm when the content of PP-g-cardanol and PP-g-MAH up to 5 and 7 phr, respectively. The results of mechanical testing showed that the tensile strength, impact strength and flexural strength of PP/ABS (70/30) blends increase with the increasing of PP-g-cardanol content up to 5 phr. The complex viscosity of PP/ABS (70/30) blends with 5 phr PP-g-cardanol showed the highest value. Moreover, the change of impact strength and tensile strength of PP/ABS (70/30) blends were investigated by accelerated degradation testing. After 4 accelerated degradation cycles, the impact strength of the PP/ABS (70/30) blends with 5 phr PP-g-cardanol decrease less than 6%, but PP/ABS (70/30) blends with 5 phr PP-g-MAH and without compatibilizer decrease as much as 12% and 32%, respectively. The tensile strength of PP/ABS (70/30) blends has a similar tendency to that of impact strength. The above results indicated that PP-g-cardanol could be used as an impact modifier and a good compatibilizer, which also exhibited better stability performance during accelerated degradation testing.

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Section: Resultsmentioning

confidence: 78%

Compatibilization of polypropylene/Poly(acrylonitrile‐butadiene‐styrene) blends by polypropylene‐graft‐cardanol

Deng

Mao

Lin

et al. 2014

J of Applied Polymer Sci

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“…Then, when the EGMA‐ g ‐SAN content is 5 phr, the storage modulus decreases. The decrease in storage modulus at the higher concentration of EGMA‐ g ‐SAN (5 phr) may be because of the plasticizing effect of the EGMA‐ g ‐SAN . At the frequency of 10 0 rad s −1 shown in Figure (b), when the EGMA‐ g ‐SAN content is 0, 1, 3, and 5 phr, the storage modulus of the blend is observed to be 3990, 4856, 5280, and 4956 Pa, respectively.…”

Section: Resultsmentioning

confidence: 92%

“…With further increase of the EGMA‐ g ‐SAN, the tensile strength of the blend also does not change appreciably. At the large amount (5 phr) of EGMA‐ g ‐SAN, the impact and tensile strengths of the blend could be the plasticizing effect of the compatibilizer in the PBT/PolyASA blend . Therefore, when 5 phr EGMA‐ g ‐SAN was added to the blend, it was thought to be an excess amount.…”

Section: Resultsmentioning

confidence: 99%

Weathering properties and hydrolysis of poly(butylene terephthalate)/poly(acrylonitrile‐co‐styrene‐co‐acrylate) blend with reactive compatibilizer

Kim

Kwon

Kim

2018

J of Applied Polymer Sci

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The effects of compatibilizer on the weathering properties and hydrolysis of the poly(butylene terephthalate) (PBT)/poly(acrylonitrile‐styrene‐acrylate) (PolyASA) blend (70/30 wt %) were investigated. Poly(ethylene‐co‐glycidylmethacrylate‐g‐styrene‐co‐acrylonitrile) (EGMA‐g‐SAN) was used as a compatibilizer of the blend. When the EGMA‐g‐SAN content was 3 phr, the impact and tensile strengths of the PBT/PolyASA blend showed maximum; as the EGMA‐g‐SAN content was increased from 0 to 3 phr, the impact strength of the blend increased from 6.1 to 9.5 kJ m−2. The rheological results showed that when the EGMA‐g‐SAN was 3 phr, the storage modulus and complex viscosity of the blend also showed maximum value. The mechanical and rheological results of the blend were consistent with the morphological result that when the EGMA‐g‐SAN was 3 phr, PolyASA domain size of the blend showed minimum. The weathering results showed that when the EGMA‐g‐SAN content was 3 phr, the gloss value of weathered surface of the blend showed maximum. After hydrolysis test, when the EGMA‐g‐SAN content was 3 phr, the impact and tensile strengths of the blend showed maximum. The mechanical, rheological, and weathering results suggested that EGMA‐g‐SAN is an effective compatibilizer in the PBT/PolyASA blend, and the optimum compatibilizer content is 3 phr. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 47197.

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“…Hong et al [83] studied the effect of PCL content (up to 5 phr) on the properties of PC/ABS (30/70 wt/wt) blend. The results are summarized in Fig.…”

Section: Polycaprolacton Systemsmentioning

confidence: 99%

Biodegradable polymer blends and composites: An overview

Hamad

Kaseem

et al. 2014

Polym. Sci. Ser. A

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Biodegradable polymers belong to a family of polymer materials that found applications ranged from medical applications including tissue engineering, wound management, drugs delivery, and orthopedic devices, to packaging and films applications. For broadening their potential applications, biodegradable polymers are modified utilizing several methods such as blending and composites forming, which lead to new materials with unique properties including high performance, low cost, and good processability. This paper reviews the recent information about the morphology of blends consisting of both biodegradable and non biodegradable polymers and associated mechanical, rheological, and thermal properties of these systems as well as their degradation behavior. In addition, the mechanical performance of composites based on biode gradable polymers is described.

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Morphological, mechanical and rheological properties of poly(acrylonitrile-butadienestyrene)/polycarbonate/poly(ε-caprolactone) ternary blends

Cited by 14 publications

References 34 publications

Compatibilization of polypropylene/Poly(acrylonitrile‐butadiene‐styrene) blends by polypropylene‐graft‐cardanol

Compatibilization of polypropylene/Poly(acrylonitrile‐butadiene‐styrene) blends by polypropylene‐graft‐cardanol

Weathering properties and hydrolysis of poly(butylene terephthalate)/poly(acrylonitrile‐co‐styrene‐co‐acrylate) blend with reactive compatibilizer

Biodegradable polymer blends and composites: An overview

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