“…Among the alkali fluoride compounds, CaF 2 is an attractive material because of its high stability and non-hygroscopic behavior. Recently, CaF 2 has attracted renewed interest as a laser material when doped with rare earths [9,10]. CaF 2 nanoparticles have been synthesized by different methods, such as the sol-gel method [11][12][13][14][15][16], solvothermal process [17,18], reverse micelle method [19,20], hydrothermal method [21], different precipitation methods [22][23][24], flame synthesis [25], etc.…”