Multi-scale structural description of siloxane–PPO hybrid ionic conductors doped by sodium salts

Chaker, Juliano Alexandre; Santilli, Celso Valentim; Pulcinelli, Sandra Helena; Dahmouche, K.; Briois, Valérie; Judeinstein, Patrick

doi:10.1039/b612587e

Cited by 41 publications

(49 citation statements)

References 45 publications

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“…In addition, blend-based polymers [93][94][95][96] and copolymerization with other polymers [85,97,98] have also been proposed as effective means to develop amorphous polymer matrixes to reduce the possibility of increasing crystallization. Other polyethers such as PPO [99,100] and nitrile-based polymer electrolytes such as PAN [101][102][103] have also have been reported. However, due to the limited space here, these will not be elaborated upon.…”

Section: Polyether-based Spesmentioning

confidence: 99%

Solid-State Electrolytes for Lithium-Ion Batteries: Fundamentals, Challenges and Perspectives

Zhao

He³

et al. 2019

Electrochem. Energ. Rev.

311

206

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With the rapid popularization and development of lithium-ion batteries, associated safety issues caused by the use of flammable organic electrolytes have drawn increasing attention. To address this, solid-state electrolytes have become the focus of research for both scientific and industrial communities due to high safety and energy density. Despite these promising prospects, however, solid-state electrolytes face several formidable obstacles that hinder commercialization, including insufficient lithium-ion conduction and surge transfer impedance at the interface between solid-state electrolytes and electrodes. Based on this, this review will provide an introduction into typical lithium-ion conductors involving inorganic, organic and inorganic-organic hybrid electrolytes as well as the mechanisms of lithium-ion conduction and corresponding factors affecting performance. Furthermore, this review will comprehensively discuss emerging and advanced characterization techniques and propose underlying strategies to enhance ionic conduction along with future development trends.

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Section: Polyether-based Spesmentioning

confidence: 99%

Solid-State Electrolytes for Lithium-Ion Batteries: Fundamentals, Challenges and Perspectives

Zhao

He³

et al. 2019

Electrochem. Energ. Rev.

311

206

View full text Add to dashboard Cite

show abstract

“…In this context, it comes up the possibility to combine organic and inorganic components, at molecular or nanometric level, generating new materials which are known as hybrid organic inorganic [1][2][3][4][5][6][7].…”

Section: Introductionmentioning

confidence: 99%

Anisotropic self-organization of hybrid silica based xerogels containing bridged positively charged 1,4-diazoniabicycle[2.2.2]octane chloride group

Arenas

Pinheiro

Ferreira

et al. 2008

Journal of Colloid and Interface Science

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“…Sodium is the second lightest and smallest alkali metal next to lithium. A source for sodium is abundant and low cost makes an essential element for large scale applications .…”

Section: Introductionmentioning

confidence: 99%

Role of ZrO₂ on physico‐chemical properties of PVA/NaClO₄ composites for energy storage applications

et al. 2016

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A novel polymer nano composite electrolyte composed of PVA polymer matrix with ZrO 2 ceramic filler and NaClO 4 salt was prepared by a solution casting. The characteristic properties of PVA/NaClO 4 polymer composite electrolytes with ZrO 2 filler were studied using FTIR, X-ray diffractometer (XRD), FESEM, DSC, AFM, AC impedance method, and cyclic voltammeter. The sample containing 3 wt% ZrO 2 exhibits good mechanical strength, high conductivity, high dielectric constant and good electrochemical response at room temperature. The conduction mechanism of the composite can be represented by the correlated barrier hopping (CBH) model and the obtained frequency dependent S parameter obeys Almond-West Universal power law. Using Williams-Landel-Ferry (WLF) and Vogel Fulcher Tamman (VTF) equations equivalence correlated the dynamic fragility (m) and activation energy (E g ) with T g of polymer composites. Transport parameters were calculated using Rice and Roth model. The cyclic voltamograms shows that the prepared films were Pseudo-capacitive in nature. POLYM. COMPOS., 00:000-000, 2016.

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Multi-scale structural description of siloxane–PPO hybrid ionic conductors doped by sodium salts

Cited by 41 publications

References 45 publications

Solid-State Electrolytes for Lithium-Ion Batteries: Fundamentals, Challenges and Perspectives

Solid-State Electrolytes for Lithium-Ion Batteries: Fundamentals, Challenges and Perspectives

Anisotropic self-organization of hybrid silica based xerogels containing bridged positively charged 1,4-diazoniabicycle[2.2.2]octane chloride group

Role of ZrO₂ on physico‐chemical properties of PVA/NaClO₄ composites for energy storage applications

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Multi-scale structural description of siloxane–PPO hybrid ionic conductors doped by sodium salts

Cited by 41 publications

References 45 publications

Solid-State Electrolytes for Lithium-Ion Batteries: Fundamentals, Challenges and Perspectives

Solid-State Electrolytes for Lithium-Ion Batteries: Fundamentals, Challenges and Perspectives

Anisotropic self-organization of hybrid silica based xerogels containing bridged positively charged 1,4-diazoniabicycle[2.2.2]octane chloride group

Role of ZrO2 on physico‐chemical properties of PVA/NaClO4 composites for energy storage applications

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Product

Resources

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Role of ZrO₂ on physico‐chemical properties of PVA/NaClO₄ composites for energy storage applications