Multiclass semi-volatile compounds determination in wine by gas chromatography accurate time-of-flight mass spectrometry

Rodríguez-Cabo, T.; Rodrı́guez, I.; Ramil, M.; Silva, A.; Cela, Rafael

doi:10.1016/j.chroma.2016.03.005

Cited by 40 publications

(17 citation statements)

References 21 publications

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“…To our knowledge the methodology for these fungicides in blueberries did not exist prior to our study. The LODs and LOQs obtained by Chen et al (2016) and Rodríguez-Cabo et al (2016) in wine, by Walorczyk (2007) in wheat grains, by Walorczyk and Drożdżyński (2012) in cereals and dry animal feed, and by Souza-Silva et al (2013) in grapes and strawberries were higher than those obtained by the present method. The LOD and LOQ ranges were 0.44-40 and 0.50-100 μg kg -1 for propiconazole I; 0.21-20 and 0.50-60 μg kg -1 for propiconazole II; and 0.16-3 and 0.55-10 μg kg -1 for tebuconazole, respectively.…”

Section: Methods Performancecontrasting

confidence: 58%

“…GC or LC are often used, alone or coupled to MS (Zamora et al 2004;Walorczyk 2007Walorczyk , 2008Economou et al 2009;Št'ávová et al 2011;Walorczyk & Drożdżyński 2012;Patyal et al 2013;Souza-Silva et al 2013;Zhang et al 2015;Chen et al 2016;Pelajić et al 2016;Rodríguez-Cabo et al 2016 (Montes et al 2009). Generally the initial application is during flowering, with others during fruit set.…”

Section: Introductionmentioning

confidence: 99%

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Development and validation of an SPME-GC method for a degradation kinetics study of propiconazole I, propiconazole II and tebuconazole in blueberries in Concordia, the main production area of Argentina

Munitz

Medina

Montti

2017

Food Additives & Contaminants: Part A

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An analytical method for the simultaneous determination of propiconazole isomers and tebuconazole residues in blueberries was developed using solid-phase microextraction (SPME) coupled to gas chromatography. Confirmation was performed by gas chromatography-mass spectrometry in selected-ion monitoring mode. The SPME fibre coating selected was CWX-DVB, and the pH was adjusted to 7 with NaOH. The method is selective with adequate precision and high accuracy and sensitivity. Recoveries ranged between 97.4% and 98.9% for all compounds; and detection and quantification limits were respectively 0.21 and 0.49 μg kg for propiconazole I; 0.16 and 0.22 μg kg for propiconazole II; and 0.16 and 0.48 μg kg for tebuconazole. The degradation of these fungicides in blueberries followed first-order rate kinetics. The half-life times for flowering and fruit set applications were respectively 4.0 and 10.3 days for propiconazole I, 4.0 and 11.4 days for propiconazole II, and 3.5 and 12.4 days for tebuconazole.

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Section: Methods Performancecontrasting

confidence: 58%

Section: Introductionmentioning

confidence: 99%

Development and validation of an SPME-GC method for a degradation kinetics study of propiconazole I, propiconazole II and tebuconazole in blueberries in Concordia, the main production area of Argentina

Munitz

Medina

Montti

2017

Food Additives & Contaminants: Part A

View full text Add to dashboard Cite

show abstract

“…Also, the relationship between esters and sensory perception of wine has been sufficiently studied. [17][18][19][20][21][22][23][24] Ethyl octanoate was found to increase red cherry aroma, the combination of ethyl octanoate and ethyl decanoate enhanced black cherry aroma of New Zealand Pinot Noir wines. [18] Moreover, other esters, such as ethyl hexanoate, ethyl acetate, ethyl 3-methylbutanoate, were also commonly detected in wine as previous studies reported.…”

Section: Introductionmentioning

confidence: 96%

Qualitative and quantitative research of propyl lactate in brewed alcoholic beverages

Sun

Yin

Zhao

et al. 2018

International Journal of Food Properties

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Recently, propyl lactate has been firstly detected in Chinese Baijiu (Chinese liquor) as one of the odor-active components. In this study, the contents of propyl lactate in other different brewed alcoholic beverages were investigated, including wine, soju, sake, vodka, rum, tequila, whisky and beer, and analyzed by solid-phase microextraction and liquid-liquid extraction coupled with gas chromatography-mass spectrometry, determined by internal standard method followed by GC-MS with selective ion monitoring. The analyses indicated that propyl lactate was present in beer and tequila samples, while not detected in other brewed alcoholic beverages. The results showed that among the 40 beer samples from 11 different countries, 36 of them contained propyl lactate at concentrations in the range of 0.23-51.71 µg L −1. In addition, all of six tequila samples contained propyl lactate at concentrations in the range of 0.77-12.14 mg L −1 , and the odor activity values (OAVs) of propyl lactate were greater than 1 in all of the tequila samples. These findings indicated that propyl lactate was widely distributed in beer and tequila; it was also an odor-active component of tequila according to OAVs.

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“…[10][11][12][13] Moreover, GC combined with solid-phase extraction technology in headspace (HS) mode has great potential in the investigation of volatile and semivolatile compounds, such as pesticides and aromatic compounds. [10,14,15] For example, GC-mass spectrometry (GC-MS) combined with solidphase extraction has been used for the determination of a group of 39 semivolatile compounds related to wine quality (pesticide residues, phenolic off-flavours, phenolic pollutants, and bioactive stilbenes). [10] Solid-phase microextraction (SPME) has also been applied in the detection of pesticides and other atmospheric contaminants by GC.…”

mentioning

confidence: 99%

“…[10,14,15] For example, GC-mass spectrometry (GC-MS) combined with solidphase extraction has been used for the determination of a group of 39 semivolatile compounds related to wine quality (pesticide residues, phenolic off-flavours, phenolic pollutants, and bioactive stilbenes). [10] Solid-phase microextraction (SPME) has also been applied in the detection of pesticides and other atmospheric contaminants by GC. [14] The combination of HS and SPME makes chromatographic detection technology more powerful.…”

mentioning

confidence: 99%

Development of a headspace solid‐phase microextraction–surface‐enhanced Raman scattering approach to detect volatile pesticides

Wang

Zhang

2018

J Raman Spectroscopy

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By coupling headspace solid‐phase microextraction (HS‐SPME) with surface‐enhanced Raman scattering (SERS), a facile and rapid method was developed for the detection of organophosphorus insecticides (phorate and isocarbophos) and organic sulfur bactericide (ferbam) in the vapour phase. Two types of SPME fibres based on stainless steel wires coated with gold (Au) nanoparticles were prepared. The fibre (Fibre II) prepared by an etching approach showed better sensitivity than did the fibre (Fibre I) prepared using a layer‐by‐layer self‐assembly method. The Raman spectra of phorate, isocarbophos, and ferbam obtained from Fibre II showed stronger and clearer characteristic peaks compared with those from Fibre I, at 634, 1,043, and 1,380 cm−1, respectively. It was found that the Raman intensity of phorate adsorbed on the Fibre II was nearly three times as high as that on Fibre I at 634 cm−1, whereas the Raman intensity of isocarbophos was around 10 times at 1,043 cm−1 and ferbam was approximately four times at 1,380 cm−1. Using Fibre II, we were able to detect vapour‐phase phorate, isocarbophos, and ferbam at concentrations as low as 0.02, 0.02, and 0.05 ppm, respectively, as well as their mixture. This approach can be simply extended to detect a wide range of volatile organic compounds and shows potential as an easier and faster alternative to gas chromatography methods for studying volatile chemicals in some cases.

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Multiclass semi-volatile compounds determination in wine by gas chromatography accurate time-of-flight mass spectrometry

Cited by 40 publications

References 21 publications

Development and validation of an SPME-GC method for a degradation kinetics study of propiconazole I, propiconazole II and tebuconazole in blueberries in Concordia, the main production area of Argentina

Development and validation of an SPME-GC method for a degradation kinetics study of propiconazole I, propiconazole II and tebuconazole in blueberries in Concordia, the main production area of Argentina

Qualitative and quantitative research of propyl lactate in brewed alcoholic beverages

Development of a headspace solid‐phase microextraction–surface‐enhanced Raman scattering approach to detect volatile pesticides

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