Multifunctional sucrose acid as a ‘green’ crosslinker for wrinkle-free cotton fabrics

Patil, Namrata V.

doi:10.1007/s10570-020-03130-9

Cited by 22 publications

(11 citation statements)

References 35 publications

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“…The transmittance peaks of the stretching vibration of C–O in C–OH groups of TAA and AA are located at 1043 cm –1 and 1210∼1240 cm –1 , respectively. Besides, the sharp transmittance peak around 1700 cm –1 is attributed to the stretching vibration of C=O in the carboxyl groups of TAA and AA, 4,27 and the spectrum of P(TAA‒AA) shows the similar transmittance peak around 1700 cm –1 . However, the transmittance peak around 800∼840 cm –1 (the stretching vibration of C=C–H) disappeared, which confirmed that the reaction of TAA and AA occurred and produced P(TAA‒AA).…”

Section: Resultsmentioning

confidence: 96%

“…Obviously, a new absorbance peak appearing at 1733 cm –1 , which is attributed to the stretching vibration of C=O in ester bonds, was observed in the Raman spectrum of the P(TAA‒AA)-modified fiber, and this new peak confirmed the esterification between P(TAA‒AA) carboxyl groups and cellulose hydroxyl groups. 4 Figure 9(b) presents the proposed ester crosslinking between P(TAA‒AA) and cellulose chains. Figure 9(c) and (d) displays the true reflection of the surface and the half cross-section of the control fiber, respectively.…”

Section: Resultsmentioning

confidence: 99%

“…However, DMDHEU-treated fabrics usually release formaldehyde during the application and storage. [4][5][6][7] Formaldehyde has been proved to be harmful to the human body; [4][5][6][7] consequently, various chemicals have been tried as finishing agents for formaldehyde-free treatment of cotton fabrics.…”

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confidence: 99%

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Preparation of multiple-reactive-site and flexible crosslinking agent with transaconitic acid and acrylic acid and its application for three-dimensional crosslinking of cellulose

Liang

Yan

Zhao

et al. 2021

Textile Research Journal

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A novel multiple-reactive-site crosslinking agent, P(TAA‒AA), was developed from transaconitic acid and acrylic acid in this study. Cotton fabrics with durable wrinkle-resistant properties were obtained by crosslinking with P(TAA‒AA), which benefited from the multifunctional carboxyl groups of crosslinking agents and the three-dimensional crosslinking inside cotton fibers. The wrinkle-resistant properties of P(TAA‒AA)-modified fabrics were evaluated and compared with those of other polycarboxylic acid-treated fabrics, and the P(TAA‒AA)-modified fabrics showed a wrinkle recovery angle of 262° as high as the 1,2,3,4-butanetetracarboxylic acid-modified fabrics while maintaining nearly two-fold higher tearing strength retention (62.9%), and they showed a much higher value of whiteness index than the citric acid-modified fabrics. This demonstrated that the obtained P(TAA‒AA) is an ideal polycarboxylic acid already known to date simultaneously to realize the high wrinkle recovery angle and high tearing strength retention for treated cotton fabrics. The Raman depth mapping images and the scanning electron microscope images of P(TAA‒AA)-modified samples indicated that P(TAA‒AA) molecules can diffuse into the amorphous regions of the cellulose fibers and form crosslinking bridges between cellulose chains. The multiple reactive carboxyl groups in P(TAA‒AA) may form three or more ester bonds between the P(TAA‒AA) molecule and different cellulose chains, which were regarded as the main contribution to the high crosslinking effectiveness of the P(TAA‒AA)-modified fabrics.

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Section: Resultsmentioning

confidence: 96%

Section: Resultsmentioning

confidence: 99%

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Preparation of multiple-reactive-site and flexible crosslinking agent with transaconitic acid and acrylic acid and its application for three-dimensional crosslinking of cellulose

Liang

Yan

Zhao

et al. 2021

Textile Research Journal

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“…It could be observed that all dyed cotton fabrics appeared a similar anthraquinone ring vibration peak of madder dye at 1597 cm −1 [2], indicating the madder dye could dye in the cotton fabrics. And all cross-linked dyed cotton fabrics appeared the ester carbonyl absorption peak near 1733 cm −1 , showing that the esterification reaction occurred between dye-polycarboxylic acid-cotton fabric [22,23]. It could be seen from Table 1, the K/S value of the direct dyed cotton fabric was 2.24, indicating that the madder dye had a poor affinity for the cotton fabric.…”

Section: Ftir and K/s Values Analysismentioning

confidence: 93%

Dyeing Property Improvement of Madder with Polycarboxylic Acid for Cotton

Cai

Zhang

et al. 2021

Polymers

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Cotton fabrics were dyed with the madder and compounds of citric acid (CA) and dicarboxylic acids [tartaric acid (TTA), malic acid (MLA), succinic acid (SUA)] as cross-linking agents and sodium hypophosphite (SHP) as the catalyst. The molecular structures and crystal structures of the dyed cotton fabrics were analyzed using Fourier-transform infrared spectroscopy (FTIR) and X-ray diffractometry (XRD), respectively. The results showed that the polycarboxylic acids esterified with the hydroxyl groups in the dye and cellulose, respectively, and the reaction mainly occurred in the amorphous region of the cotton fabric. Compared with the direct dyed cotton fabric, the surface color depth (K/S) values of the CA, CA+TTA, CA+MLA, CA+SUA cross-linked dyed cotton fabrics increased by approximately 160%, 190%, 240%, 270%, respectively. The CA+SUA cross-linked dyed cotton fabric achieved the biggest K/S value due to the elimination of the negative effect by α-hydroxyl in TTA and MLA on esterification reaction, and the cross-linked dyed cotton fabrics had great levelness property. The washing and rubbing fastness of the cross-linked cotton fabrics were above four levels. The light resistance stability and the antibacterial property of the cross-linked dyed cotton fabrics was obviously improved. The sum of warp and weft wrinkle recovery angle (WRA) of the CA+SUA cross-linked dyed cotton fabric was 55° higher than that of raw cotton fabric, and its average UV transmittance for UVA was less than 5% and its UPF value was 50+, showing a great anti-wrinkle and anti-ultraviolet properties.

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“…5a. In the control sample, the broad spectrum in between 3100 and 3600 cm -1 is attributed to the -OH group of the cotton (Patil and Netravali 2020). The strong band with maxima at 1043 cm -1 is the illustrated characteristics due to overlapping of C-C, C-O, and C-O-C functional groups of cotton while the peak at 1635.1 cm -1 might be due to the presence of water in cotton (Doh et al 2013).…”

Section: Crease Recovery Angle (Cra) and Physical Propertiesmentioning

confidence: 95%

Copper nanoparticles induced, trimesic acid grafted cellulose–an effective, non-hazardous processing approach for multifunctional textile with low chemical induction

et al. 2021

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Cross-linkers have great importance in textile due to the widespread utilization of cellulosic fibers for clothing. Unfortunately, the acute toxicity of formaldehyde-based resins and the poor performance of non-formaldehyde resins still keep the research door open for scientists in this area. Herein, we demonstrated copper nanoparticles induced trimesic acid grafted cellulose as a sustainable solution for multifunctional easy-care clothing. Our treated fabric presents crease recovery angle value of 248°comparable to that of most promising citric acid-based cross-

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Multifunctional sucrose acid as a ‘green’ crosslinker for wrinkle-free cotton fabrics

Cited by 22 publications

References 35 publications

Preparation of multiple-reactive-site and flexible crosslinking agent with transaconitic acid and acrylic acid and its application for three-dimensional crosslinking of cellulose

Preparation of multiple-reactive-site and flexible crosslinking agent with transaconitic acid and acrylic acid and its application for three-dimensional crosslinking of cellulose

Dyeing Property Improvement of Madder with Polycarboxylic Acid for Cotton

Copper nanoparticles induced, trimesic acid grafted cellulose–an effective, non-hazardous processing approach for multifunctional textile with low chemical induction

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