With the continuous improvement of people’s living standards, the requirements of music majors for their training standards are also increasing, which leads to the development of music training in the direction of intelligence. This paper discusses the problems of breathing, coordination, and muscle control ability in vocal training and puts forward a vocal training method based on dynamic adjustment factor and Monte Carlo algorithm to solve the difficult problem of vocal training for college students and understand the relationship between vocal training and exercise. Firstly, the sports training set and vocal pronunciation training set are constructed in the form of clustering, and the samples in the set are analyzed discretely to ensure that the samples conform to normal distribution; then, using the Monte Carlo algorithm analyzes the two sample sets and finds out the relationship between exercise and vocal training. Finally, according to breathing, coordination, muscle control ability, and other indicators, calculate the impact of exercise on vocal sound. MATLAB simulation shows that the method proposed in this paper can analyze the influence of exercise on vocal vocalization from the perspective of breathing, coordination, muscle control ability, and other indicators. The accuracy of judgment results is more than 95%, and the time is less than 1 min. All indicators are better than traditional vocal training methods (90%, 2 min), which shows the effectiveness of the method proposed in this paper.