Multilevel-Regulated Metal–Organic Framework Platform Integrating Pore Space Partition and Open-Metal Sites for Enhanced CO₂ Photoreduction to CO with Nearly 100% Selectivity

Band edge modulation via a hydrogen-bond-free cation in hybrid bismuth iodine for overall photocatalytic CO2 reduction

“…S17†). 32,33 Fig. 5c displays the evolution of the active species on the photocatalyst surface under constant visible light irradiation.…”

“…The occurrence of these intense peaks indicates the presence of a strong interaction between the adsorbed CO 2 and the photocatalyst and the efficient activation and conversion of the CO 2 molecules under visible light irradiation. 32,33…”

Highly efficient photoelectrocatalytic oxidation of arsenic(iii) with a polyoxometalate-thiacalix[4]arene-based metal–organic complex-modified bismuth vanadate photoanode

“…Recently, MOC- and POM-based photocatalysts have gained significant attention owing to their potential photocatalytic performances. 40–47 POM-based metal–organic complexes (PMOCs) with the combined advantages of both POMs and MOCs have received growing interest due to their unique properties and prospective applications. 48,49 Recent studies have proved that PMOCs are efficient photocatalyst candidates for organic synthesis, CO 2 reduction, H 2 production, pollutant removal, etc .…”

Photosensitizing metal covalent organic framework with fast charge transfer dynamics for efficient CO2 photoreduction

“…5–8 To date, despite the exploration of various photocatalytic materials for the CO 2 RR, the catalytic performances are severely restricted by their poor visible-light absorption, low charge separation efficiency, and less efficacious catalytic sites. 9–11 Thus, there is a strong need to develop better photocatalysts for the CO 2 RR.…”