Na₃SbS₃: Single Crystal X‐ray Diffraction, Raman Spectroscopy, and Impedance Measurements

Abstract

Abstract. Na 3 SbS 3 was prepared by the reaction of anhydrous Na 2 S, antimony, and sulfur in a ratio of 3:2:3 at 870 K. The pale yellow compound is air and moisture sensitive. A microcrystalline sample was obtained after annealing Na 3 SbS 3 for two weeks at 720 K. The crystal structure of Na 3 SbS 3 was determined by single-crystal X-ray diffraction at 123 K. Na 3 SbS 3 crystallizes in the cubic space group P2 1 3 (No. 198) with a = 8.6420(1) Å, V = 645.42(1) Å 3 and Z = 4. The structure refinement converged to R = 0.0099 (wR = 0.0181) for 592 independent reflections and 23 parameters. Na 3 SbS 3 is isotypic with Na 3 AsS 3 . Sodium atoms are located on three different sites, which show a

Bis(2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)nickel(II) bis(perchlorate) hemihydrate

“…Na 3 SbS 3 was prepared by a reported procedure (Pompe & Pfitzner, 2013). Ni(ClO 4 ) 2 Á6H 2 O (36.6 mg, 0.1 mmol), terpyridine (46.7 mg, 0.2 mmol) and Na 3 SbS 3 (172.2 mg, 0.6 mmol) were reacted under solvothermal conditions in 2 ml H 2 O at 443 K for 26.5 h in an 11 ml glass tube.…”

Li17Sb13S28: A New Lithium Ion Conductor and addition to the Phase Diagram Li2S–Sb2S3

“…Such so-called secondary bondsa re also known for other thiometalate compounds, for example, MnSb 2 S 4 , [37] Li 3 SbS 3 , [8] or Na 3 SbQ 3 (Q = S, Se). [9,11] A survey of the length distribution of secondary bonds in thioantimonates(III) shows ap references for such distances in the range from 2.9 and 3.25 . [49] Six of the [SbS 5 E] units are connected by sharing four basal corners and are arranged around one vacancy in the anion lattice, see Figure 1.…”

[Mn(terpy)Sb2S4]n, a 1D Network of MnSb4S5 Rings Exhibiting a Pronounced Magnetocaloric Effect and Luminescence

“…[Mn(terpy) 2 ](ClO 4 ) 2 was synthesized following an analogous method to prepare [Ni(bipy) 3 ]Cl 2 •5H 2 O described by Ruiz-Pèrez et al, [73] and Na 3 SbS 3 was synthesized after Pompe and Pfitzner. [74] Generally, the reaction products were filtered off, washed with small amounts of water and dried under ambient conditions. For the magnetic and luminescent investigations, the products were additionally cleaned with numerous ultrasonic treatment steps in acetone and ethanol.…”