Nanoreactors in action for a durable microactuator using spontaneous combustion of gases in nanobubbles

Abstract

A number of recent studies report enhancement of chemical reactions on water microdroplets or inside nanobubbles in water. This finding promises exciting applications, although the mechanism of the reaction acceleration is still not clear. Specifically, the spontaneous combustion of hydrogen and oxygen in nanobubbles opens the way to fabricate truly microscopic engines. An example is an electrochemical membrane actuator with all three dimensions in the micrometer range. The actuator is driven by short voltage pulses of alternating polarity, which generate only nanobubbles. The device operation is, however, restricted by a fast degradation of the electrodes related to a high current density. Here it is demonstrated that the actuator with ruthenium electrodes does not show signs of degradation in the long-term operation. It is the only material able to withstand the extreme conditions of the alternating polarity electrolysis. This property is due to combination of a high mechanical hardness and metallic conductivity of ruthenium oxide. The actuator combines two features considered impossible: on-water catalysis and combustion in a microscopic volume. It provides an exceptional opportunity to drive autonomous microdevices especially for medical or biological applications.