“…These complex models include various thermophysical parameters, such as the acentric factor ω, in their functional forms, and therefore the number of active degrees of freedom, N, no longer represents molecular complexity, as discussed by Guardone & Argrow (2005). Therefore, the minimum value of the fundamental derivative in the vapour phase, Γ min , which occurs at a state point along the VLE line, is used in the following Stewart, Jacobsen & Penocello (1969), Lambrakis & Thompson (1972), Cramer (1989Cramer ( , 1991, Guardone & Argrow (2005), Nannan et al (2007) and Colonna et al ( , 2008b.…”