Net front-side displacement reactions in a carborane system: halide-exchange reactions among derivatives of closo-2,4-dicarbaheptaborane, 2,4-C2B5H7

Ng, Bradford; Onak, Thomas; Fuller, Keith

doi:10.1021/ic00219a034

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Net front-side displacement reactions in a carborane system: halide-exchange reactions among derivatives of closo-2,4-dicarbaheptaborane, 2,4-C2B5H7

Abstract: Halogen exchange is observed between B‐halo derivatives of closo‐2,4‐C2B5H‐, and tetraalkylammonium halides (tab.) and appears possible only when the reagent halide ion is smaller than the leaving halide.

Cited by 6 publications

References 1 publication

ChemInform Abstract: Net Front‐Side Displacement Reactions in a Carborane System: Halide‐Exchange Reactions Among Derivatives of closo‐2,4‐Dicarbaheptaborane, 2,4‐C₂B₅H₇ .

ChemInform Abstract: Net Front‐Side Displacement Reactions in a Carborane System: Halide‐Exchange Reactions Among Derivatives of closo‐2,4‐Dicarbaheptaborane, 2,4‐C₂B₅H₇ .

Elements of group 3

Intermediate carboranes

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Net front-side displacement reactions in a carborane system: halide-exchange reactions among derivatives of closo-2,4-dicarbaheptaborane, 2,4-C2B5H7

Abstract: Halogen exchange is observed between B‐halo derivatives of closo‐2,4‐C2B5H‐, and tetraalkylammonium halides (tab.) and appears possible only when the reagent halide ion is smaller than the leaving halide.

Cited by 6 publications

References 1 publication

ChemInform Abstract: Net Front‐Side Displacement Reactions in a Carborane System: Halide‐Exchange Reactions Among Derivatives of closo‐2,4‐Dicarbaheptaborane, 2,4‐C2B5H7 .

ChemInform Abstract: Net Front‐Side Displacement Reactions in a Carborane System: Halide‐Exchange Reactions Among Derivatives of closo‐2,4‐Dicarbaheptaborane, 2,4‐C2B5H7 .

Elements of group 3

Intermediate carboranes

Contact Info

Product

Resources

About

ChemInform Abstract: Net Front‐Side Displacement Reactions in a Carborane System: Halide‐Exchange Reactions Among Derivatives of closo‐2,4‐Dicarbaheptaborane, 2,4‐C₂B₅H₇ .

ChemInform Abstract: Net Front‐Side Displacement Reactions in a Carborane System: Halide‐Exchange Reactions Among Derivatives of closo‐2,4‐Dicarbaheptaborane, 2,4‐C₂B₅H₇ .