New developments in the Pd-catalysed cyclisation-coupling reaction of alkene-containing carbonucleophiles with organic halides (and triflates). The first examples of asymmetric catalysis.

Bruyere, Didier; Monteiro, Nuno; Bouyssi, Didier; Balme, Geneviève

doi:10.1016/s0022-328x(03)00700-9

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Direct Alkyne Functionalization2

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Cited by 6 publications

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“…This type of reaction could also be done with the nucleophilic capture of an intermediate palladium π-complex in a Wacker-type process (Scheme 43). 95 Thus, bromides 210 or 211, in the presence of Pd(OAc) 2 and DPPE, underwent cyclization to the corresponding products 212 and 213 as single isomers in 58% and 48% yields, respectively. 96 An interesting multicomponent reaction has been developed by the Larock group involving the direct addition of aryl boronic acids to alkynes (Scheme 44).…”

Section: Direct Alkyne Functionalizationmentioning

confidence: 99%

“…This type of reaction could also be done with the nucleophilic capture of an intermediate palladium π-complex in a Wacker-type process (Scheme ) . Thus, bromides 210 or 211 , in the presence of Pd(OAc) 2 and DPPE, underwent cyclization to the corresponding products 212 and 213 as single isomers in 58% and 48% yields, respectively …”

Section: 7 Direct Alkyne Functionalizationmentioning

confidence: 99%

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