New electrochemical sensor for the detection of hydrogen sulfide and other redox active species

Spilker, Björn; Randhahn, Jean; Grabow, Harald; Beikirch, Helmut; Jeroschewski, Paul

doi:10.1016/j.jelechem.2007.09.019

Cited by 83 publications

(33 citation statements)

References 39 publications

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“…In these conditions, more advanced instrumental methods have also been developed for determination of hydrogen sulfide like inductively coupled plasma-atomic emission spectroscopy (Pouly et al 1999), hydride generation-atomic fluorescence spectrometry (Jin et al 2007), electrochemistry (Lawrence et al 2004;Spilker et al 2008;Tsai et al 2006;García-Calzada et al 1999;He et al 2002;Doeller et al 2005), ion chromatography (Giuriati et al 2004;Divjak and Goessler 1999) and chemiluminescence (Lawrence et al 2000;Huang et al 2007;Maya et al 2007;Safavi and Karimi 2002;Du et al 2001). However, development of simple methods which does not require sophisticated instruments is a permanent requirement.…”

Section: Introductionmentioning

confidence: 99%

Spectrophotometric determination of hydrogen sulfide in environmental samples using sodium 1,2-naphthoquinone-4-sulfonate and response surface methodology

Shariati-Rad

Irandoust

Jalilvand

2016

Int. J. Environ. Sci. Technol.

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A simple spectrophotometric method for determination of hydrogen sulfide in wastewater and hot spring samples was developed. The method is based on the reaction between hydrogen sulfide and sodium 1,2-naphthoquinone-4-sulfonate (NQS). The effect of various experimental factors on the reaction between hydrogen sulfide and NQS was investigated and optimized using central composite design. The optimal values of the factors were 5.00 9 10 -4 mol L -1 for concentration of NQS and 1.00 9 10 -2 mol L -1 for concentration of hydrochloric acid. The wavelength of the maximum absorption of the reaction product was 320 nm. Constructed calibration curve for hydrogen sulfide determination was linear in the range of 0.5-20.0 mg L -1 with the detection limit of 0.16 mg L -1 . The method was free from interferences. Percent relative errors below 2 % were obtained for determination of hydrogen sulfide in environmental samples.

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Section: Introductionmentioning

confidence: 99%

Spectrophotometric determination of hydrogen sulfide in environmental samples using sodium 1,2-naphthoquinone-4-sulfonate and response surface methodology

Shariati-Rad

Irandoust

Jalilvand

2016

Int. J. Environ. Sci. Technol.

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“…[29][30][31][32][33][34][35] A required condition of redox cycling is the presence of equal amounts of the reduced and the oxidized species. If the concentration of the oxidized species is lower than that of the reduced one, two possibilities can be predicted.…”

Section: Introductionmentioning

confidence: 99%

Salt-free electrolysis of water facilitated by hydrogen gas in thin layer cell

Li¹,

Aoki²,

Chen³

et al. 2013

RIE

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“…SECM is widely studied for example by Kwak and Bard [2]. The redox cycling sensor [3,4] is an alternative to amperometric sensors for measuring concentrations of redox active species and features a lower expected detection limit.…”

Section: Introductionmentioning

confidence: 99%

“…1. The complete method and necessary electrode geometry was described in detail by Jeroschewski et al [3,5] and Spilker [4].…”

Section: Introductionmentioning

confidence: 99%

“…As the resulting current i is proportional to the mediator concentration, it is possible to determine the change in mediator concentration [6,7], and through calibration the analyte concentration beyond the membrane. The sensor is well described in detail in [3][4][5], including the function of guard and counter electrodes, which is not the focus of this paper.…”

Section: Introductionmentioning

confidence: 99%

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