New estertin derivatives based on trivacant Keggin-type [β-SbW9O33]9− cluster

Zhang, Lancui; Han, Xue; Zhu, Zai‐Ming; Wang, Qiu-Xue; You, Weixiong; Li, Yangguang; Wang, Enbo

doi:10.1016/j.inoche.2010.02.015

Cited by 26 publications

(6 citation statements)

References 41 publications

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“…The Mn–O distances are in the range of 2.049(14)–2.300(15) Å. Furthermore, the estertin precursor [Sn(CH 2 ) 2 COOCH 3 ] 3+ hydrolyzes into carboxyethyltin [Sn(CH 2 ) 2 COOH] 3+ during the reaction process; such a phenomenon has never been observed in our recent reports on POM-estertin derivatives. − But the difference is that the original Sn–O carboxyl bond is broken resulting in the cyclic carboxyethyltin converted into a chain structure (see Scheme ).…”

Section: Resultsmentioning

confidence: 90%

“…Organotin decorated POMs are a class of fascinating POM derivatives in POM-based organic–inorganic functionalization. − The charge density of oxygen ions on the surface of POMs would change after organotin decorating, which could adjust the electronic characteristic and redox properties of POMs. We have successfully obtained five ring carboxyethyltin decorated POM derivatives by introducing a carboxyl group into the POM skeleton. − Herein, we synthesized the first single crystal sandwich-type germanotungstates functionalized by open chain carboxyethyltin ( 1 ). The carboxylic acid anchoring group could guarantee the loading of POMs on TiO 2 and tight electron coupling.…”

Section: Introductionmentioning

confidence: 99%

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A Novel Carboxyethyltin Functionalized Sandwich-type Germanotungstate: Synthesis, Crystal Structure, Photosensitivity, and Application in Dye-Sensitized Solar Cells

Sang

Zhang

et al. 2014

ACS Appl. Mater. Interfaces

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A novel sandwich-type germanotungstate [C(NH2)3]10[Mn2{Sn(CH2)2COOH}2(B-α-GeW9O34)2]·8H2O (1) represents the first single crystalline polyoxometalate (POM) functionalized by open chain carboxyethyltin, which was designed and synthesized in aqueous solution and applied to a dye-sensitized solar cell (DSSC) for the first time. Its photosensitivity was explored through a fluorescence spectrum (FL), surface photovoltage spectrum (SPV), electrochemical method, and solid diffuse spectrum. 1 displays the primary features of sensitizers in DSSCs, and the efficiency of the solar cell is 0.22%. Delightedly, when 1 was employed to assemble a cosensitized solar cell configuration by preparing a 1-doped TiO2 electrode and additionally adsorbing N719 dyes, a considerably improved efficiency was achieved through increasing spectral absorption and accelerating electron transport, which is 19.4% higher than that of single N719 sensitization. This result opens up a new way to position different dyes on a single TiO2 film for cosensitization.

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Section: Resultsmentioning

confidence: 90%

Section: Introductionmentioning

confidence: 99%

A Novel Carboxyethyltin Functionalized Sandwich-type Germanotungstate: Synthesis, Crystal Structure, Photosensitivity, and Application in Dye-Sensitized Solar Cells

Sang

Zhang

et al. 2014

ACS Appl. Mater. Interfaces

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“…Figure b presents the simplified 2D stacking alignment of 1 . For all we know, this alluring structure has first been observed within OTLnHPOMs, representing a rare example of a POM fragment concurrently including Ln 3+ cations, OT groups, and pyridinecarboxylate ligands with respect to those only comprising OT or Ln 3+ components or both with isolated structures. − ,, …”

Section: Resultsmentioning

confidence: 95%

“…For all we know, this alluring structure has first been observed within OTLnHPOMs, representing a rare example of a POM fragment concurrently including Ln 3+ cations, OT groups, and pyridinecarboxylate ligands with respect to those only comprising OT or Ln 3+ components or both with isolated structures. [25][26][27][28][29][30][31]44,45 FL Studies. Owing to the particular electron-structure features of Ln 3+ ions, Ln 3+ sustained attraction in biomedical sensory probe lasers, kinescopes, projected displays, and plasma displays.…”

Section: ■ Introductionmentioning

confidence: 99%

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Organic–Inorganic Two-Dimensional Hybrid Networks Constructed from Pyridine-4-Carboxylate-Decorated Organotin–Lanthanide Heterometallic Antimotungstates

Pang

Gong

et al. 2020

Inorg. Chem.

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Six organic−inorganic hybrid pyridine-4-carboxylate-decorated organotin (OT)−lanthanide (Ln) heterometallic antimotungstates 3+ (2), Pr 3+ (3), Nd 3+ (4), Sm 3+ (5), Eu 3+ (6); Hpca = isonicotinic acid] have been prepared with the help of the structuredirecting effect of the trivacant [B-α-SbW 9 O 33 ] 9− segment toward [(CH 3 ) 2 Sn] 2+ and Ln 3+ ions in an acidic water medium. The prominent architecture characteristic is that their structural units consist of a trivacant [B-β-SbW 9 O 33 ] 9− segment stabilized by three [Sn-(CH 3 ) 2 (H 2 O)] 2+ groups and a [Ln(H 2 O) 6 (pca)] 2+ cation, which are interconnected to propagate an intriguing two-dimensional (2D) network. For all we know, 1−6 stand for the first 2D OT−Ln heterometallic polyoxometalates. Furthermore, luminescence performances of solid-state 3−6 were deeply surveyed at ambient temperature. Energy migration from [B-β-SbW 9 O 33 ] 9− and pca − to Sm 3+ centers in 5 was also studied. Comparative studies demonstrate that the contribution of [B-β-SbW 9 O 33 ] 9− sensitizing the emission of Sm 3+ is prominently larger than that of pca − sensitizing the emission of Sm 3+ in the emission process of 5. Most interestingly, 6 as a fluorescence probe exhibits high selectability and sensitivity for recognizing Zn 2+ and Cu 2+ in water.

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Organoantimony(III)‐Containing Tungstoarsenates(III): From Controlled Assembly to Biological Activity

Yang

Bassil

Lin

et al. 2015

Chemistry A European J

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A family of three sandwich-type, phenylantimony(III)-containing tungstoarsenates(III), [(PhSb(III) ){Na(H2 O)}As(III) 2 W19 O67 (H2 O)](11-) (1), [(PhSb(III) )2 As(III) 2 W19 O67 (H2 O)](10-) (2), and [(PhSb(III) )3 (B-α-As(III) W9 O33 )2 ](12-) (3), have been synthesized by one-pot procedures and isolated as hydrated alkali metal salts, Cs3 K3.5 Na4.5 [(PhSb(III) ){Na(H2 O)}As(III) 2 W19 O67 (H2 O)]⋅41H2 O (CsKNa-1), Cs4.5 K5.5 [(PhSb(III) )2 As(III) 2 W19 O67 (H2 O)]⋅35H2 O (CsK-2), and Cs4.5 Na7.5 [(PhSb(III) )3 (B-α-As(III) W9 O33 )2 ]⋅42H2 O (CsNa-3). The number of incorporated {PhSb(III) } units could be selectively tuned from one to three by careful control of the reaction parameters. The three compounds were characterized in the solid state by single-crystal XRD, IR spectroscopy, and thermogravimetric analysis. The aqueous solution stability of sandwich polyanions 1-3 was also studied by multinuclear ((1) H, (13) C, (183) W) NMR spectroscopy. Effective inhibitory activity against six different kinds of bacteria was identified for all three polyanions, for which the activity increased with the number of incorporated {PhSb(III) } groups.

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New estertin derivatives based on trivacant Keggin-type [β-SbW9O33]9− cluster

Cited by 26 publications

References 41 publications

A Novel Carboxyethyltin Functionalized Sandwich-type Germanotungstate: Synthesis, Crystal Structure, Photosensitivity, and Application in Dye-Sensitized Solar Cells

A Novel Carboxyethyltin Functionalized Sandwich-type Germanotungstate: Synthesis, Crystal Structure, Photosensitivity, and Application in Dye-Sensitized Solar Cells

Organic–Inorganic Two-Dimensional Hybrid Networks Constructed from Pyridine-4-Carboxylate-Decorated Organotin–Lanthanide Heterometallic Antimotungstates

Organoantimony(III)‐Containing Tungstoarsenates(III): From Controlled Assembly to Biological Activity

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