New insight into the activity of ZSM-5 supported Co and CoRu bifunctional Fischer–Tropsch synthesis catalyst

Fischer–Tropsch synthesis over Pd promoted cobalt based mesoporous supported catalyst

“…Among the transition metals, ruthenium, nickel, cobalt and iron are the most common metals used for FT catalyst. Cobalt is an active metal for the synthesis of long-chain hydrocarbons due to its high activity and selectivity towards paraffins, low Water-Gas Shift (WGS) activity, lower CO 2 selectivity, and less oxygenates formation [4][5][6]. Many researchers have studied the effect of different oxide supports (titania, silica, alumina, zirconia, etc.)…”

Fischer–Tropsch synthesis using Co and Co-Ru bifunctional nanocatalyst supported on carbon nanotube prepared via chemical reduction method

“…Moreover, it has been shown that the two factors of metal dispersion and its interaction with the support material play major role in catalytic performance of FTS. Recently, some new supports have been used in the numerous studies such as carbon nanotubes (CNTs), γ -Al 2 O 3 nanofibers, carbon sphere, zeolites (e.g., ZSM-5), graphene and the ordered mesoporous SiO 2 (e.g., [3,[22][23][24][25][26][27][28][29] . Using CNT as the support in Co-based catalysts leads to decreasing the reduction temperature of the catalysts during the pretreatment stage [3,8,15] .…”

Ultrasensitive hydrazine sensor fabrication based on Co-doped ZSM-5 zeolites for environmental safety

“…52,53 The detection of Co 3 O 4 oxide is in agreement with other data in the literature for cobalt-containing ZSM-5 zeolites prepared by different routes. 4,5,54 It was shown that the low angle diffraction peaks of ZSM-5 zeolite are sensitive to the presence of impurities or species inside the zeolite channels; and, therefore, they are used to calculate the variation in crystallinity accompanying the zeolites aer synthesis treatments. 55 From an inspection of the low angle diffraction peaks in Fig.…”

“…Cobalt-containing ZSM-5 zeolites have drawn a great deal of attention in recent years. They have been used as catalysts for a wide range of important chemical reactions, such as oxidation of styrene and a-pinene, 1,2 direct conversion of syngas to gasoline range hydrocarbons, 3 Fischer-Tropsch synthesis, 4 combustion of isopropanol, 5 oxidation of methane to methanol and formaldehyde 6,7 and ammoxidation of ethane 8 and ethylene. 9 High activity was reported for nitrogen oxides abatement over Co-ZSM-5 catalysts.…”