New International Formulation for the Viscosity of H2O

Huber, Marcia L.; Perkins, Robert L.; Laesecke, Arno; Friend, Daniel G.; Sengers, J. V.; Assael, Marc J.; Metaxa, Ifigeneia N.; Vogel, E.; Mareš, Radim; Miyagawa, Kiyoshi

doi:10.1063/1.3088050

Cited by 373 publications

(307 citation statements)

References 107 publications

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“…The product of viscosity and mobility should therefore be constant. As the temperature dependence of water viscosity is well tabulated [e.g., Huber et al, 2009], this offers the possibility to infer the ionic mobility at any temperature T from b(T 0 ), h(T 0 ) and h(T)…”

Section: Dependence On Temperaturementioning

confidence: 99%

Dependence of spectral‐induced polarization response of sandstone on temperature and its relevance to permeability estimation

Zisser¹,

Kemna²,

Nover³

2010

J. Geophys. Res.

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[1] The possibility to estimate permeability from the electrical spectral induced polarization (SIP) response might be the most important benefit offered by SIP measurements. It can thus be deduced that, in the future, SIP measurements will be carried out more frequently at the field scale or in a well-logging context to estimate permeability. In the shallow subsurface, however, the temperature generally exhibits seasonal variability, and in the deeper subsurface, it usually increases with depth. Hence, knowledge about the dependence of the SIP response on temperature is necessary in order to avoid possible misinterpretation of datasets impacted by thermal effects. In our study, we present a semiempirical framework to describe the temperature dependence of the SIP response. We briefly introduce the SIP response and its relation to permeability in terms of an electrochemical polarization mechanism and combine this formulation with relationships for the dependence of ionic mobility on temperature. We compare the predictions of our formulation with the experimental data from SIP measurements performed on sandstone at temperatures from 0°C to 80°C. The measured SIP response was transformed into a relaxation time distribution, using the empirical Cole-Cole model and a regularized Debye decomposition procedure. The SIP response was found to be in good agreement with the theoretical model. The temperature dependence of both direct current conductivity and relaxation time is controlled mainly by the dependence of ionic mobility on temperature, and the shape of the relaxation time distribution of the investigated sandstone is almost independent of temperature. The temperature effect on the SIP response can therefore be easily corrected.Citation: Zisser, N., A. Kemna, and G. Nover (2010), Dependence of spectral-induced polarization response of sandstone on temperature and its relevance to permeability estimation,

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Section: Dependence On Temperaturementioning

confidence: 99%

Dependence of spectral‐induced polarization response of sandstone on temperature and its relevance to permeability estimation

Zisser¹,

Kemna²,

Nover³

2010

J. Geophys. Res.

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“…10 The viscosity data set is consistent with the recent recommendations of IAPWS which are based on a critical analysis of data sets for water published between 1914 and 2007. 5 The Kestin data set 3 was chosen as it is specific to the saturation line and is more precise than the IAPWS recommendations.…”

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confidence: 99%

Communications: The fractional Stokes–Einstein equation: Application to water

Harris

2010

The Journal of Chemical Physics

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“…In particular, the extensive work on the viscosity and thermal conductivity of carbon dioxide [1] and ethane [2,3] by the IUPAC Subcommittee on Transport Properties [now known as the International Association for Transport Properties (IATP)] and on water [4][5][6] by the International Association for the Properties of Water and Steam (IAPWS) and IATP has influenced the present project.…”

Section: Preamblementioning

confidence: 99%

“…In practice, correlations for the viscosity can be formulated as either a summation or a product of contribution terms. It is common to include the initial density dependence in the residual term and fit the initial density dependence along with the higher-order residual terms [1,5]. It is also common to group the dilute-gas, first-density, and residual viscosity into the background viscosity [1] to isolate the critical enhancement contribution to the viscosity.…”

Section: Viscositymentioning

confidence: 99%

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Reference correlations for the viscosity and thermal conductivity of fluids over an extended range of conditions: hexane in the vapor, liquid, and supercritical regions (IUPAC Technical Report)

Perkins

Huber

Assael

et al. 2015

Pure and Applied Chemistry

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This article summarizes the correlation procedures developed for IUPAC Project 2012-040-1-100 [Reference correlations for the thermal conductivity and viscosity of fluids over extended range of conditions (vapor, liquid and supercritical regions)]. This project is focused on the development of wide-range reference correlations for the thermal conductivity and viscosity of fluids that incorporate as much theoretical knowledge of these properties as possible. The thermal conductivity and viscosity correlations developed here for pure fluids are functions of temperature and density. The best available equations of state for a given fluid are used to calculate the thermodynamic properties required for these correlations, often from measured temperatures and pressures. The correlation methodology developed during this project has been applied to hexane in this report but can be applied to any pure fluid with a reliable equation of state and reliable data for the thermal conductivity and viscosity over a significant range of temperatures and densities.

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New International Formulation for the Viscosity of H2O

Cited by 373 publications

References 107 publications

Dependence of spectral‐induced polarization response of sandstone on temperature and its relevance to permeability estimation

Dependence of spectral‐induced polarization response of sandstone on temperature and its relevance to permeability estimation

Communications: The fractional Stokes–Einstein equation: Application to water

Reference correlations for the viscosity and thermal conductivity of fluids over an extended range of conditions: hexane in the vapor, liquid, and supercritical regions (IUPAC Technical Report)

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