New Layered Mixed Metal Phosphonates for High Dielectric−Polymer Composite Materials

Abstract

New layered 1:1 mixed Ba 2+ /Ti 4+ metal phosphonates, BaTi(O 3 PC 6 H 5 ) 3 and SrTi(O 3 PC 6 H 5 ) 3 , have been prepared via a hydrothermal route, in which mixed metal oxides, BaTiO 3 and SrTiO 3 , were reacted with phenyl phosphonic acid. The mixed-metal phosphonates were combined with polystyrene (PS) via a solution route and cast as thin films for dielectric permittivity measurements. The composites exhibit an enhancement in the dielectric permittivity as a function of weight loading relative to the parent mixed metal oxide-PS composites.

Polymer Composite and Nanocomposite Dielectric Materials for Pulse Power Energy Storage

“…New layered 1:1 mixed Ba 2+ /Ti 4+ metal phosphonates, BaTi(C 6 H 5 PO 3 ) 3 and SrTi(C 6 H 5 PO 3 ) 3 , have been prepared from reacting BaTiO 3 and SrTiO 3 with phenyl phosphonic acid [ 96 ]. The mixed-metal phosphonates were combined with polystyrene (PS) via a solution route and spin casted into thin films.…”

A review on hybrid nanolaminate materials synthesized by deposition techniques for energy storage applications

“…Dielectric capacitors that have desirable attributes for portable electronic devices, such as energy density, power density and rate capability, are not available and are under current investigation. 125 The energy density of a dielectric capacitor can be calculated from 125…”

“…Polymers exhibit high values of dielectric breakdown eld strength (E BD ). 125 In addition to this, polymers are processable, which is another advantage. However, the dielectric constants for polymers are frequently low.…”

Preparation and characterization of upconversion luminescent NaYF4:Yb, Er (Tm)/PS bulk transparent nanocomposites through in situ polymerization

“…Among the broad variety of available polymers, polystyrene (PS) is one of the most popular and extensively-used polymers because of its excellent transparency and processing properties. Many diverse inorganic groups have been incorporated into polystyrene for preparation of composite spheres [40][41][42][43][44][45][46][47][48][49][50][51][52][53][54][55] and thin films [56,57]. But to our knowledge, there are few reports available in the literature on the generation of bulk polystyrene composite materials.…”