New mixed ligand oxido-vanadium(V) complexes with O,O-donor and diimine ligands: Synthesis, crystal structure and catalytic activity in eco-friendly oxidation of olefins and phenol

Sultana, Sazida Yasmin; Sharma, Mitu; Talukdar, Hiya; Begum, Tahshina; Gour, Nand Kishor; Sarma, Bipul; Islam, Nashreen S.

doi:10.1016/j.mcat.2024.114352

Molecular Catalysis

2024

DOI: 10.1016/j.mcat.2024.114352

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New mixed ligand oxido-vanadium(V) complexes with O,O-donor and diimine ligands: Synthesis, crystal structure and catalytic activity in eco-friendly oxidation of olefins and phenol

Sazida Yasmin Sultana,

Mitu Sharma,

Hiya Talukdar

et al.

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2024

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Magneto-Structural Correlation in µ-Hydroxo-µ-Carboxylato Hetero-Bridged Dinuclear Oxidovanadium(IV) Complexes

Yoshida,

Koikawa,

Tokii

2024

Crystals

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Hetero-bridged dinuclear oxidovanadium(IV) complexes, [(VO)2{HB(pz}3}2(μ-OH)(μ-O2CR)] [R = C2H5, 1; (CH3)3C, 2; (CH3)3CCH2, 3; Ph2CH, 4; Ph3C, 5; PhCH2CH2, and 6; {HB(pz)3}− = hydrotris(pyrazolyl)borate], were synthesized and characterized using X-ray crystallography, infrared spectroscopy, UV-VIS spectroscopy, and elemental analysis. Structure analysis revealed that these complexes adopt a μ-hydroxo-μ-carboxylato hetero-bridged dinuclear structure. Magnetic measurements revealed ferromagnetic interactions (J ~ +20 cm−1) between two V(IV) ions.

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Magneto-Structural Correlation in µ-Hydroxo-µ-Carboxylato Hetero-Bridged Dinuclear Oxidovanadium(IV) Complexes

Yoshida,

Koikawa,

Tokii

2024

Crystals

View full text Add to dashboard Cite

show abstract

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New mixed ligand oxido-vanadium(V) complexes with O,O-donor and diimine ligands: Synthesis, crystal structure and catalytic activity in eco-friendly oxidation of olefins and phenol

Cited by 1 publication

References 110 publications

Magneto-Structural Correlation in µ-Hydroxo-µ-Carboxylato Hetero-Bridged Dinuclear Oxidovanadium(IV) Complexes

Magneto-Structural Correlation in µ-Hydroxo-µ-Carboxylato Hetero-Bridged Dinuclear Oxidovanadium(IV) Complexes

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