New soft porous frameworks based on lambda-zirconium phosphate and aliphatic dicarboxylates: Synthesis and structural characterization

Alhendawi, Hussein; Brunet, Ernesto; Juanes, Olga; Hammouda, Huda; Idhair, Salem; Payán, Elena Rodríguez; Rodríguez, María de Victoria

doi:10.1016/j.jpcs.2015.06.021

Cited by 7 publications

(6 citation statements)

References 23 publications

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“…inside the interlayer galleries of ZrP. Accordingly, new tailored organic-inorganic materials for many scientific applications can be obtained [33,34]. …”

Section: Phosphoric Acid Industry -Problems and Solutionsmentioning

confidence: 99%

“…As we mentioned earlier, a layer of phosphates sustains the zirconium metals whose apical bonds are bonded to negative and neutral basic species, both pointing to the interlayer space (bottom of Figure 1). In the starting lambda structure, each zirconium is typically bonded to chloride anion and neutral Phosphoric Acid Industry -Problems and Solutionsdimethylsulphoxide molecule [48,49] which, in principle, can be replaced by any organic chemical structure, that is, carboxylates and amines, in a topotactic manner [32][33][34]45]. Recently, we have prepared several new soft and rigid phosphate-based λ-type organic-inorganic two-dimensional (2D) and 3D frameworks with variable porosity [10,20,32,34].…”

Section: Design Processing and Applications Of Zrp-based Porous Matementioning

confidence: 99%

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Phosphate-Based Organic-Inorganic Hybrid Materials: Design, Construction and Technological Applications

Alhendawi¹,

Brunet²,

Payán³

2017

Phosphoric Acid Industry - Problems and Solutions

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The art of designing and synthesizing organic molecules has reached very high levels of sophistication, based on a relatively simple set of rules that guide both the invention and synthesis of new compounds. This set of rules is construed as the rational synthetic method of organic chemistry. As material chemists confronted to the task of building new solid structures with tailored chemical properties, we do inevitably need to develop some rational approach and to establish the corresponding set of rules allowing a realistic level of predictive knowledge in the construction of solid scaffolds. These conditions are reasonably accomplished by the use of layered salts of tetravalent transition metals, namely zirconium phosphate (ZrP). The placing of organic molecules between the layers of ZrP is quite straightforward, can easily be controlled and leads to enduring, solid materials where the confinement makes the organic molecules to show new properties at the supramolecular level. The chemistry of metal phosphates/phosphonates will be detailed in relation with the following topics: (i) molecular recognition, (ii) chemically driven porosity changes, (iii) chiral memory and supramolecular chirality, (iv) luminescence signalling, (v) photo-induced electron-transfer processes, (vi) hydrogen storage, (vii) confinement of drugs and (viii) metal uptake.

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“…inside the interlayer galleries of ZrP. Accordingly, new tailored organic-inorganic materials for many scientific applications can be obtained [33,34]. …”

Section: Phosphoric Acid Industry -Problems and Solutionsmentioning

confidence: 99%

Section: Design Processing and Applications Of Zrp-based Porous Matementioning

confidence: 99%

Phosphate-Based Organic-Inorganic Hybrid Materials: Design, Construction and Technological Applications

Alhendawi¹,

Brunet²,

Payán³

2017

Phosphoric Acid Industry - Problems and Solutions

Self Cite

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“…Therefore, all the attempts to replace the fluoride ligand of the F-phase with other organic or inorganic ones were unsuccessful [11]. On the contrary, several organic and inorganic derivatives have been prepared using the more reactive Cl-phase as precursor [1][2][3][4][5][6][7][8][9][10][11][12][13][14][15][16].…”

Section: Introductionmentioning

confidence: 99%

“…In this context, there are very few examples in the literature about the synthesis of organic-or inorganic-inorganic materials based on k-ZrP [11][12][13][14][15][16]. Therefore, any contribution to investigate the potential of this substrate can be of interest.…”

Section: Introductionmentioning

confidence: 99%

“…Our recent successful synthesis of soft porous layered pillared materials based k-ZrP, EDTA [12] and a series of flexible alkandioic acids of different chain length [13,14] has stimulated our interest in the preparation of rigid mircoporous k-type materials. To accomplish this task the present work is planned to be the consequence of one main synthetic goal: construction of a new rigid microporous organic-inorganic hybrid material based on k-ZrP and 1,4-biphenyldicarboxylate.…”

Section: Introductionmentioning

confidence: 99%

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Lambda-zirconium phosphate covalently pillared with 1,4-biphenyldicarboxylate: a new λ-type rigid microporous framework

Alhendawi

2016

J Incl Phenom Macrocycl Chem

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A new layered pillared material [ZrPO 4 (-OH) 0.60 (C 14 H 8 O 4 ) 0.20 (CH 3 ) 2 SO] based on k-zirconium phosphate (k-ZrP) and 1,4-biphenyldicarboxylic acid (bpdc) has been prepared. The synthesized material is characterized by X-ray diffractometry, FT-IR spectrophotometry, elemental, thermogravimetric and N 2 adsorption/ desorption analyses. The used analysis techniques reveal that the bpdc is successfully incorporated inside the interlayer region of k-ZrP. Regarding the N 2 adsorption/desorption analysis of k-ZrP-bpdc, it gives a moderate specific area of 98 m 2 g -1 and an average pore diameter of 0.88 nm. Therefore, a new k-type rigid microporous framework is obtained. From the practical perspective, there would be a good potential for implementing applications of ZrPO 4 (OH) 0.60 (C 14 H 8 O 4 ) 0.20 (CH 3 ) 2 SO in the fields of inclusion chemistry, molecular shape recognition and heterogeneous catalysis.Graphical abstract A new layered pillared material [ZrPO 4 (OH) 0.60 (C 14 H 8 O 4 ) 0.20 (CH 3 ) 2 SO] based on k-zirconium phosphate (k-ZrP) and 1,4-biphenyldicarboxylic acid (bpdc) has been prepared. The synthesized material is characterized by X-ray diffractometry, FT-IR spectrophotometry, elemental, thermogravimetric and N 2 adsorption/ desorption analyses. The used analysis techniques reveal that the bpdc is successfully incorporated inside the interlayer region of k-ZrP. Regarding the N 2 adsorption/desorption analysis of k-ZrP-bpdc, it gives a moderate specific area of 98 m 2 g -1 and an average pore diameter of 0.88 nm. Therefore, a new k-type rigid microporous framework is obtained. From the practical perspective, there would be a good potential for implementing applications of ZrPO 4 (OH) 0.60 (C 14 H 8 O 4 ) 0.20 (CH 3 ) 2 SO in the fields of inclusion chemistry, molecular shape recognition and heterogeneous catalysis.

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Poly(decamethylene terephthalamide) copolymerized with long‐chain alkyl dodecanedioic acid: Toward bio‐based polymer and improved performances

Zou

Wang

Feng

et al. 2018

J of Applied Polymer Sci

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Poly(decamethylene terephthalamide) (PA10T), a bio‐based high‐performance semi‐aromatic polyamide, has been commercialized in recent years. However, there still are some weaknesses restricting its application range, such as narrow melt processing window and low ductility. In this study, we chose dodecanedioic acid (a potential bio‐based raw material) as the comonomer to prepare copolyamides [poly(decamethylene terephthalamide/decamethylene dodecanediamide), PA10T/1012] for solving these problems. The basic properties of these copolyamides were characterized by viscosity measurement, Fourier transform infrared spectrometer, proton nuclear magnetic resonance, wide‐angle X‐ray diffraction, differential scanning calorimetry, thermogravimetric analysis, dynamic mechanical analysis, and tensile measurement. Results show that, compared to PA10T, PA10T/1012 exhibits wider melt processing window and more outstanding elongation at break. Meanwhile, PA10T/1012 is still qualified for high temperature resistant material. Furthermore, Tg, Td,5%, Td,10%, and Td,max of PA10T/1012 show a linear dependence on 1012 content, which is helpful to design new bio‐based copolyamides for meeting the needs of various occasions. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018, 135, 46531.

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New soft porous frameworks based on lambda-zirconium phosphate and aliphatic dicarboxylates: Synthesis and structural characterization

Cited by 7 publications

References 23 publications

Phosphate-Based Organic-Inorganic Hybrid Materials: Design, Construction and Technological Applications

Phosphate-Based Organic-Inorganic Hybrid Materials: Design, Construction and Technological Applications

Lambda-zirconium phosphate covalently pillared with 1,4-biphenyldicarboxylate: a new λ-type rigid microporous framework

Poly(decamethylene terephthalamide) copolymerized with long‐chain alkyl dodecanedioic acid: Toward bio‐based polymer and improved performances

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