The art of benchmarking study has improved at an astonishing rate the scientific research in all areas but mainly in microwave engineering domain, and in particular, the field of microwave (MW) and radiofrequency (RF) integrated circuit design. Moreover, the fast simulation of complex MF/RF structures is considered a big challenge for the simulators, mainly in light of the continuous information and communication technology (ICT) development. In this context, the present paper sets out to present two important numerical electromagnetic (EM) methods, the method of moments (MOM) and our advanced transverse wave approach (A-TWA) for full-wave analysis of RF/MW structures. The computational complexity of these methods is evaluated. Two complex printed antennas working in the RF/MW range are selected and investigated. The EM problems that can be found in these circuits and that could not be solved analytically or by other numerical methods are discussed. The EM-validation of the studied structures using A-TWA and MOM is demonstrated and compared in the context of RF/MW applications. The obtained simulation results prove the efficiency and rapidity of our approach in comparison with the literature.