Activated carbon (AC) derived from coconut shells (Tra Bac Company, Vietnam) is a promising candidate material for the capacitance deionization (CDI) technology due to their low-cost, abundance and its high surface area. In our work, the composites AC/MCNTs electrodes were prepared using the polyvinyl alcohol (PVA) and glutaric anhydride (GA) as cross-linking binder. The morphological properties were investigated by scanning electron microscopy (SEM). The electrochemical properties were performed by electrochemical measurements such as: cyclic voltammetry (CV), cyclic charge – discharge (CDC). The composite electrode with 1% CNTs (wt.) showed encouragingly a specific capacitance of 94.0 F/g and a salt absorption capacity of 11.2 mg/g with stable performance.