Nitrite selective anion receptor based on 1-methyl-1H-perimidine

Pandian, Thiravidamani Senthil; Srinivasadesikan, Venkatesan; Lin, Ming‐Chang; Kang, Jongmin

doi:10.1016/j.tet.2015.02.091

Cited by 11 publications

(2 citation statements)

References 43 publications

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“…Mahapatra et al [155] synthesized a novel perimidine-boron complex 37 and evaluated them for selective detection of fluoride ion from fluorometric and colorimetric method. Another new anion receptor combined with 1-methyl-1 H-perimidine 38 was synthesized by Pandian et al [156]. This perimidine receptor was complexed with Cl − , Br − , NO 2 − , and I − anions through hydrogen bonding.…”

Section: Miscellaneous Applicationsmentioning

confidence: 99%

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Recent Advances in the Synthesis of Perimidines and their Applications

Sahiba¹,

Agarwal²

2020

Top Curr Chem (Z)

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Perimidines are versatile scaffolds and a fascinating class of N-heterocycles that have evolved significantly in recent years due to their immense applications in life sciences, medical sciences, and industrial chemistry. Their ability of molecular interaction with different proteins, complex formation with metals, and distinct behavior in various ranges of light makes them more appealing and challenging for future scientists. Various novel technologies have been developed for the selective synthesis of perimidines and their conjugated derivatives. These methods extend to the preparation of different bioactive and industrially applicable molecules. This review aims to present the most recent advancements in perimidine synthesis under varied conditions like MW radiation, ultrasound, and grinding using different catalysts such as ionic liquids, acid, metal, and nanocatalyst and also under green environments like catalyst and solvent-free synthesis. The applications of perimidine derivatives in drug discovery, polymer chemistry, photo sensors, dye industries, and catalytic activity in organic synthesis are discussed in this survey. This article is expected to be a systematic, authoritative, and critical review on the chemistry of perimidines that compiles most of the state-of-art innovation in this area.

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Section: Miscellaneous Applicationsmentioning

confidence: 99%

“…Another new anion receptor combined with 1-methyl-1 H -perimidine 38 was synthesized by Pandian et al . [ 156 ]. This perimidine receptor was complexed with Cl − , Br − , NO 2 − , and I − anions through hydrogen bonding.…”

Section: Applications In Various Fieldsmentioning

confidence: 99%

Recent Advances in the Synthesis of Perimidines and their Applications

Sahiba¹,

Agarwal²

2020

Top Curr Chem (Z)

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Differential Recognition of Various Anions Utilizing Aromatic CH Hydrogen Bonding

Han

Sohn

Cho

et al. 2018

Bulletin Korean Chem Soc

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Dihydrogen phosphate selective anion receptors 1, 2, and 3 that utilize amide N H, and C H for anion recognition have been designed and synthesized. For 1 and 2, aromatic C H hydrogen bonding element is present on naphthyl rings (H a ). In addition, for receptor 1, this aromatic hydrogen bonding element is further polarized by the nitro groups, which would enhance the hydrogen bonding ability. Partial charges derived from Natural Population Analysis also supported the existence of this polarization. That is, positive partial charge of H a in receptor 1 was more positive than that in receptor 2. As expected from the partial charge values, receptor 1 consistently showed highest affinity among three receptors, followed by receptor 2 regardless of the anions tested in this study. Therefore, we have shown that affinity modulation of a receptor was possible by changing the nature of the aromatic C H hydrogen. In addition, the receptors showed selectivity toward dihydrogen phosphate among various anions including acetate and chloride.

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