2024
DOI: 10.1021/acs.inorgchem.4c02169
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No Switching Cooperativity between Coordinated Azo Ligands on Complexes Having {MII(phosphane-κ2P)}2+ (M = Pd, Pt) Scaffolds

Ot Raïch Panisello,
Jesús Jover,
Cristina Puigjaner
et al.

Abstract: A series of square-planar palladium and platinum compounds with cis-blocking phosphanes and terminal azobenzene ligands [M(dppp)-(azo) 2 ](OTf) 2 (azo = CN(C 6 H 4 )-N�N-(C 6 H 4 )CN (iso-cyano), CN-(C 6 H 4 )-N�N-(C 6 H 5 ) (iso-Ph)) and [{M 2 (tpbz)}(azo) 4 ](OTf) 4 (azo = CN(C 6 H 4 )-N�N-(C 6 H 5 ) (iso-Ph)) have been synthesized and fully characterized. Similarly to the uncoordinated ligands, the new coordination compounds have shown to be photochemically active with respect to their trans-to-cis isomeriz… Show more

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