Non-aqueous energy-efficient absorbents for CO2 capture based on porous silica nanospheres impregnated with amine

Controlling Gas Selectivity in Molecular Porous Liquids by Tuning the Cage Window Size

“…PLs can be categorized by their composition: Type 1 PLs are neat molecular liquids containing internal cavities; Type 2 PLs (Figure b) are solutions of porous molecules in a solvent that is size‐excluded from the pores; and Type 3 PLs are dispersions of porous particles suspended in a cavity excluded liquid . Examples of all three types of PL have been described recently, and molecular simulations have led to a better understanding of their microstructure …”

The dynamic CO2 adsorption of polyethylene polyamine-loaded MCM-41 before and after methoxypolyethylene glycol codispersion

“…[1][2][3] Solid amine adsorption technology, with weak corrosivity, highly efficient adsorption performance and low regeneration energy consumption, is recognized as an effective method. [4][5][6][7] So far the study of amine-loaded solid sorbents mainly focuses on immobilizing amines onto the inner surface of porous supporting materials, such as metal-organic frameworks (MOFs), [8][9][10][11][12][13] mesoporous molecular sieves, 14-22 silicas [23][24][25][26][27][28][29][30][31] and so on. [32][33][34][35][36][37][38][39][40] Chen et al incorporated polyethyleneimine (PEI) into mesoporous zeolite 13X prepared by pore-expanding original micropores; due to PEI-dispersion in mesopores, the CO 2 adsorption capacity for PEI-modied 13X reached 80 mg g À1 at 100 C under a pure CO 2 atmosphere.…”

Controlling Gas Selectivity in Molecular Porous Liquids by Tuning the Cage Window Size

“…PLs can be categorized by their composition: Type 1 PLs are neat molecular liquids containing internal cavities; Type 2 PLs (Figure 1b) are solutions of porous molecules in a solvent that is size-excluded from the pores; and Type 3 PLs are dispersions of porous particles suspended in a cavity excluded liquid. [4] Examples of all three types of PL have been described recently, [5][6][7][8][9][10][11][12] and molecular simulations have led to a better understanding of their microstructure. [13][14][15][16] Porous organic cages (POCs) are a relatively new class of microporous solids that, unlike extended frameworks, are constructed from discrete organic molecules.…”