Non-classical hydrogen bonding involving bound diazides in an inositol derivative

Abstract

Key indicatorsSingle-crystal X-ray study T = 88 K Mean (C-C) = 0.016 Å Disorder in solvent or counterion R factor = 0.053 wR factor = 0.127 Data-to-parameter ratio = 9.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e. # 2006 International Union of Crystallography Printed in Great Britain -all rights reserved The inositol derivative 1d-1,2-diazido-1,2-dideoxy-3,4,5,6tetra-O-benzyl-myo-inositol diethyl ether 0.6-solvate, C 34 H 34 N 6 O 4 Á0.6C 4 H 10 O, packs with weak and unusual C-HÁ Á ÁN,O hydrogen bonds and C-HÁ Á Á interactions.Figure 1The molecular structure of (I), with displacement ellipsoids drawn at the 50% probability level. The solvent molecule has been omitted. organic papers