Notizen: Na<sub>3</sub>O(CN) — das erste Alkalimetallchalkogenidpseudohalogenid / Na<sub>3</sub>O(CN) — the First Alkali Metal Chalcogenide Pseudohalide

Einkristallstrukuruntersuchungen zufolge leitet sich die Kristallstruktur von Na3O(CN)=(CN)ONa3 vom Antiperowskittyp ab (a = 454,3(1) pm, Pm3m); das Cyanidanion ist fehlgeordnet. Oberhalb von 230°C ist Na3O(CN) ein schneller Natriumionenleiter. Die hohe Natriumionenbeweglichkeit resultiert zum einen aus der Rotationsdiffusion des CN−‐Anions (Drehtüreffekt) und zum anderen aus dem Teilschmelzen der Kationenstruktur.

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Kristallstruktur von gelbem K₃OBr

Sitta

Hippler

Vogt

et al. 1991

Zeitschrift anorg allge chemie

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Notizen: Na₃O(CN) — das erste Alkalimetallchalkogenidpseudohalogenid / Na₃O(CN) — the First Alkali Metal Chalcogenide Pseudohalide

Abstract: The colourless compound Na3O(CN) has been prepared. The characterization by X-ray powder methods leads to a cubic primitive lattice (P m 3 m) with a = 456(2) pm (Z = 1). The structure is related to the anti-perovskite type.

Cited by 5 publications

References 0 publications

ChemInform Abstract: Na3O(CN) ‐ The First Alkali Metal Chalcogenide Pseudohalide

ChemInform Abstract: Na3O(CN) ‐ The First Alkali Metal Chalcogenide Pseudohalide

(CN)ONa₃, Kristallstruktur und Natriumionenleitfähigkeit

Kristallstruktur von gelbem K₃OBr

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Notizen: Na3O(CN) — das erste Alkalimetallchalkogenidpseudohalogenid / Na3O(CN) — the First Alkali Metal Chalcogenide Pseudohalide

Abstract: The colourless compound Na3O(CN) has been prepared. The characterization by X-ray powder methods leads to a cubic primitive lattice (P m 3 m) with a = 456(2) pm (Z = 1). The structure is related to the anti-perovskite type.

Cited by 5 publications

References 0 publications

ChemInform Abstract: Na3O(CN) ‐ The First Alkali Metal Chalcogenide Pseudohalide

ChemInform Abstract: Na3O(CN) ‐ The First Alkali Metal Chalcogenide Pseudohalide

(CN)ONa3, Kristallstruktur und Natriumionenleitfähigkeit

Kristallstruktur von gelbem K3OBr

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Notizen: Na₃O(CN) — das erste Alkalimetallchalkogenidpseudohalogenid / Na₃O(CN) — the First Alkali Metal Chalcogenide Pseudohalide

(CN)ONa₃, Kristallstruktur und Natriumionenleitfähigkeit

Kristallstruktur von gelbem K₃OBr