Novel Phosphorus-Nitrogen-Containing Ionic Liquid Modified Metal-Organic Framework as an Effective Flame Retardant for Epoxy Resin

Huang, Rong; Guo, Xiuyan; Ma, Shiyue; Xie, Jixing; Xu, Jin-Quan; Ma, Jing

doi:10.3390/polym12010108

Cited by 57 publications

(34 citation statements)

References 42 publications

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“…This hierarchical strategy simultaneously improved the fire safety of UP and its mechanical property. Similar strategy was also reported by encapsulating P and N containing ionic liquid (IL) into MOF (NH2-MIL-101(Al)) as novel FR for EP [ 83 ], which solved the poor dispersion and neutralizing the effect of directly adding IL into polymers. This IL-modified MOF combined the advantages of both materials and exhibited the 51% and 37.8% reduction in pHRR and SPR, respectively.…”

Section: Mof Applied In Fire Retardancy Researchmentioning

confidence: 77%

Recent Progress on Metal–Organic Framework and Its Derivatives as Novel Fire Retardants to Polymeric Materials

Zhang

et al. 2020

Nano-Micro Lett.

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High flammability of polymers has become a major issue which has restricted its applications. Recently, highly crystalline materials and metal–organic frameworks (MOFs), which consisted of metal ions and organic linkers, have been intensively employed as novel fire retardants (FRs) for a variety of polymers (MOF/polymer). The MOFs possessed abundant transition metal species, fire-retardant elements and potential carbon source accompanied with the facile tuning of the structure and property, making MOF, its derivatives and MOF hybrids promising for fire retardancy research. The recent progress and strategies to prepare MOF-based FRs are emphasized and summarized. The fire retardancy mechanisms of MOF/polymer composites are explained, which may guide the future design for efficient MOF-based FRs. Finally, the challenges and prospects related to different MOF-based FRs are also discussed and aim to provide a fast and holistic overview, which is beneficial for researchers to quickly get up to speed with the latest development in this field.

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Section: Mof Applied In Fire Retardancy Researchmentioning

confidence: 77%

Recent Progress on Metal–Organic Framework and Its Derivatives as Novel Fire Retardants to Polymeric Materials

Zhang

et al. 2020

Nano-Micro Lett.

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“…Moreover, the nanoscale metal ions/clusters in MOFs play an important role in improving the FR and smoke suppression performances. Up to now, several metal centers have been selected to research the MOF-derived FRs, such as Co, 7 − 9 Zn, 10 − 12 Zr, 13 − 15 Al, 16 , 17 Fe, 18 − 20 Cu, 21 , 22 Ni, 23 − 25 Sn, 26 and Mo. 27 Hu et al have found that 2D layered and 3D block MOFs combining common transition metals (such as Fe, Co, Zr, and Ni) and rigid organic complexes showed better flame retardancy with less dosage.…”

Section: Introductionmentioning

confidence: 99%

Comparative Study on the Flame Retardancy and Retarding Mechanism of Rare Earth (La, Ce, and Y)-Based Organic Frameworks on Epoxy Resin

Zhang

et al. 2021

ACS Omega

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In this work, a series of rare earth-based metal–organic frameworks (RE-MOFs) with the same organic ligand were synthesized and studied as flame retardants on epoxy. Through thermogravimetric analysis, limiting oxide index, UL-94, and cone calorimeter tests, a Y-based MOF (Y-MOF) showed the best flame retardancy compared with a La-based MOF (La-MOF) and Ce-based MOF (Ce-MOF). Further research with Raman, X-ray photoelectron spectroscopy, and theoretical calculation revealed that the reasons for the different flame retardance performances of RE-MOFs resulted from the catalytic carbonizing abilities and the radical-trapping abilities of La, Ce, and Y.

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“…Once these FRs enter the environment, they can easily attach to any airborne particle and can travel distances far from their emission or production sites. Hence, traces of such non-biodegradable FRs can be found in freshwater, food products, ecosystems, or can even be inhaled if they are present in the air [ 20 ]. On the other hand, biodegradable FRs are the one that can be degraded by microorganisms in the soil or water and result in mineralization.…”

Section: Introductionmentioning

confidence: 99%

Biodegradable Flame Retardants for Biodegradable Polymer

Maqsood

Seide

2020

Biomolecules

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To improve sustainability of polymers and to reduce carbon footprint, polymers from renewable resources are given significant attention due to the developing concern over environmental protection. The renewable materials are progressively used in many technical applications instead of short-term-use products. However, among other applications, the flame retardancy of such polymers needs to be improved for technical applications due to potential fire risk and their involvement in our daily life. To overcome this potential risk, various flame retardants (FRs) compounds based on conventional and non-conventional approaches such as inorganic FRs, nitrogen-based FRs, halogenated FRs and nanofillers were synthesized. However, most of the conventional FRs are non-biodegradable and if disposed in the landfill, microorganisms in the soil or water cannot degrade them. Hence, they remain in the environment for long time and may find their way not only in the food chain but can also easily attach to any airborne particle and can travel distances and may end up in freshwater, food products, ecosystems, or even can be inhaled if they are present in the air. Furthermore, it is not a good choice to use non-biodegradable FRs in biodegradable polymers such as polylactic acid (PLA). Therefore, the goal of this review paper is to promote the use of biodegradable and bio-based compounds for flame retardants used in polymeric materials.

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Novel Phosphorus-Nitrogen-Containing Ionic Liquid Modified Metal-Organic Framework as an Effective Flame Retardant for Epoxy Resin

Cited by 57 publications

References 42 publications

Recent Progress on Metal–Organic Framework and Its Derivatives as Novel Fire Retardants to Polymeric Materials

Recent Progress on Metal–Organic Framework and Its Derivatives as Novel Fire Retardants to Polymeric Materials

Comparative Study on the Flame Retardancy and Retarding Mechanism of Rare Earth (La, Ce, and Y)-Based Organic Frameworks on Epoxy Resin

Biodegradable Flame Retardants for Biodegradable Polymer

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