Novel push–pull heterocyclic azo disperse dyes containing piperazine moiety: Synthesis, spectral properties, antioxidant activity and dyeing performance on polyester fibers

Mohammadi, Asadollah; Khalili, Behzad; Tahavor, Marzieh

doi:10.1016/j.saa.2015.06.024

Cited by 63 publications

(34 citation statements)

References 39 publications

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“…In contrast to marketed dyes of molecular structure 8 , dyes 7 show light brown to orange‐red shades, whereas dyes 8 show yellow shades, which may be attributed to the presence of aryl or alkyl substituent at carbon C‐3 of dye 8 , which restricts the conjugation with the amino group through a push‐pull system,23 and hence the amino group in 7 participate in the conjugation of that dyes as shown in Figure 1. Such observation would be an indication that 7 is the true structure form.…”

Section: Resultsmentioning

confidence: 96%

“…Furthermore, fused pyrazoles can function as sedative‐hypnotic medications and non‐nucleoside HIV‐1 reverse transcriptase inhibitors 20,21. Azo‐based disperse dyes can be synthesized from a variety of heterocyclic intermediates to afford heteroaromatic azo disperse dyes with good tinctorial strength and brighter coloration properties than those derived from aromatic azo components 22,23…”

Section: Introductionmentioning

confidence: 99%

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Microwave‐Assisted Synthesis of Arylazoaminopyrazoles as Disperse Dyes for Textile Printing

Khattab

Haggag

Elnagdi

et al. 2016

Zeitschrift anorg allge chemie

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The synthesis of heterocyclic azo-dyes via conventional heating and microwave (MW) heating was investigated. From a sequence of reactions starting from cyanoacetic acid, 4-arylazo-2H-pyrazol-3-ylamines and 4-arylazo-2-phenyl-2H-pyrazol-3-ylamines were obtained. The structures these compounds were obtained by inspection 766 of spectroscopic and analytical techniques including 1 H and 13 C NMR spectroscopy, IR spectroscopy, mass spectrometry, and elemental analysis. The fastness properties and UV/Vis absorption spectroscopic data of these disperse dyes in printing polyester fabrics were investigated.

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Section: Resultsmentioning

confidence: 96%

Section: Introductionmentioning

confidence: 99%

Microwave‐Assisted Synthesis of Arylazoaminopyrazoles as Disperse Dyes for Textile Printing

Khattab

Haggag

Elnagdi

et al. 2016

Zeitschrift anorg allge chemie

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“…Four disperse TCFH dyestuffs 3a‐d was applied to polyester fibers at 2 % shade employing the high temperature pressure technique. The measurement of dye uptake into polyester fibers was determined by absorption route according to Beer Lambert law …”

Section: Resultsmentioning

confidence: 99%

“…Therefore, many researchers have synthesized hydrazones as target structures and explored their biological activities. These remarks highlight the need for the development of innovative hydrazones that acquire various biological activities …”

Section: Introductionmentioning

confidence: 99%

Synthesis, Solvatochromism, Antibacterial Activity and Dyeing Performance of Tricyanofuran‐Hydrazone Analogues

et al. 2016

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Four novel tricyanofuran disperse dyestuffs 3a‐d bearing hydrazone moiety were synthesized in order to investigate their possible antibacterial activity. The hydrazone moiety was introduced via azo‐coupling of the tricyanofuran with the appropriately functionalized diazonium salt. The optical properties of these compounds showed interesting solvatochromic properties. The absorption peaks are observed in the wavelength range 454–513 nm. It can also be seen that they display different maximum emissions in the wavelength range 528–615 nm. The functional groups attached to the hydrazone moiety influenced both on absorption and emission maxima. The prepared hydrazone‐based disperse dyes were applied for dyeing polyester fabrics, affording satisfactory results. Furthermore, compounds 3a and 3c demonstrated a relatively strong antibacterial activity against some selected gram positive Staphylococcus aureus and Bacillus subtilis; and gram negative Escherichia coli and Pseudomonas aeuroginosa employing Ampicillin as standard drug.

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“…Imidazole ring is an important pharmacophore in drug discovery. Extensive biochemical and pharmacological studies have confirmed that imidazole molecule is associated with a wide range of biological activities including anticancer [8,9], antibacterial [10], antifungal [11], antioxidant [12], antihypertensive [13] and anticoagulant [14], properties. In recent years, there have been important applications of azo dye was permeate into the field of electronic industry as a strong components in the DVD-R (digital versatile disc-recordable) because of its characteristic as stable metal azo dyes.…”

Section: Introductionmentioning

confidence: 99%

Synthesis, Spectral, Thermal and Biological Studies of Some Metal Complexes Derived from Heterocyclic Mono Azo Dye Ligand 2'[(2'-Hydroxy-4-methyl phenyl)azo]imidazole

Al-Adilee¹,

Atyha²

2018

Asian J. Chem.

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Asian Journal of Chemistry; Vol. 30, No. 2 (2018), 280-292 in the azo dyes compounds, such as hydroxyl, carboxylic acid, halogens, esters and amines [19,20]. An important uses of azo imidazole compounds used analytical reagents for solvent extraction to determination of some metal ions [21,22]. The heterocyclic azo imidazole compounds have important role in spectral determination field to determine the trace amount of elements especially transition metal ions and heavy metals because of high sensitivity and selectivity [23,24].The present work describes the synthesis and spectral characterizations of 2'[2'-(1-hydroxy-4-methyl phenyl)azo]-imidazole (HMePAI = HL), containing phenolic-OH function and imidazole moiety. The heterocyclic mono azo dye ligand and its metal complexes were studied by various spectral analysis and screened for their biological activities. As well as the study of ligand and Ni(II) complex of prescription drug anticancer by using the lines of cancerous liver cells of the type HePG2 and compared with line of the ordinary cells.

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Novel push–pull heterocyclic azo disperse dyes containing piperazine moiety: Synthesis, spectral properties, antioxidant activity and dyeing performance on polyester fibers

Cited by 63 publications

References 39 publications

Microwave‐Assisted Synthesis of Arylazoaminopyrazoles as Disperse Dyes for Textile Printing

Microwave‐Assisted Synthesis of Arylazoaminopyrazoles as Disperse Dyes for Textile Printing

Synthesis, Solvatochromism, Antibacterial Activity and Dyeing Performance of Tricyanofuran‐Hydrazone Analogues

Synthesis, Spectral, Thermal and Biological Studies of Some Metal Complexes Derived from Heterocyclic Mono Azo Dye Ligand 2'[(2'-Hydroxy-4-methyl phenyl)azo]imidazole

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