“…13 Films about 2 m thick were produced by spin coating from a solution of the polymer in chloroform. Before performing the experiments, the films were heated at 80°C ͑well above the glass transition and the mesophase range of the polymer͒ in order to erase any thermal history or previously induced effects.…”
Biphotonic holographic gratings have been recorded in a side-chain azobenzene liquid crystalline polyester using a blue incoherent source and a He–Ne laser. Intensity gratings and the appearance of surface relief have been observed when two linearly polarized beams from a He–Ne laser are made to interfere on a film illuminated with blue light. Polarized holographic gratings are also created with two orthogonally circularly polarized He–Ne beams. All these gratings are stable in darkness but can be erased with blue light.
“…13 Films about 2 m thick were produced by spin coating from a solution of the polymer in chloroform. Before performing the experiments, the films were heated at 80°C ͑well above the glass transition and the mesophase range of the polymer͒ in order to erase any thermal history or previously induced effects.…”
Biphotonic holographic gratings have been recorded in a side-chain azobenzene liquid crystalline polyester using a blue incoherent source and a He–Ne laser. Intensity gratings and the appearance of surface relief have been observed when two linearly polarized beams from a He–Ne laser are made to interfere on a film illuminated with blue light. Polarized holographic gratings are also created with two orthogonally circularly polarized He–Ne beams. All these gratings are stable in darkness but can be erased with blue light.
“…The cross like structure was observed in the case of several amorphous azobenzene polymers such as E1aP, DNO [13,16] and azobenzene dendrimers. However, no anisotropy could be induced in liquid crystalline polymers such as E1a12 or P6a12 [17]. However, in the…”
Section: Film Between Crossed Polarizersmentioning
Abstract:We demonstrate a new type of anisotropy in thin films of amorphous azobenzene polymers induced between 570 and 633 nm, where the absorbance in the film is on the order of 0.05. The anisotropy has a pronounced radial contribution. This observation points to an additional mechanism for the alignment of azobenzene molecules.
“…Wendorff et al showed that holographic gratings could be inscribed in LC polymers composed of AZ moieties and photoinert mesogenic groups Anderle & Wendorff, 1994). Hvilsted et al achieved holographic gratings with diffraction efficiencies of about 40% in AZ-containing LC polyesters (Hvilsted et al, 1995). Recently, formation of holographic gratings in side-chain LC polymers containing AZ moieties by means of photochemical phase transition was intensively studied.…”
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