Novel sulfur-based electrolyte additive for constructing high-quality sulfur-containing electrode-electrolyte interphase films in sodium-ion batteries

Li, Jianhui; Fan, Ziqiang; Ye, Haiping; Zheng, Junyang; Qiu, Jingwei; He, Haoxuan; Liu, Peng; He, Mingxi; Liu, Haidong; Duc Hoa, Nguyen; Zeng, Ronghua

doi:10.1016/j.cej.2024.151188

Chemical Engineering Journal

2024

DOI: 10.1016/j.cej.2024.151188

|View full text |Cite

Novel sulfur-based electrolyte additive for constructing high-quality sulfur-containing electrode-electrolyte interphase films in sodium-ion batteries

Jianhui Li,

Ziqiang Fan,

Haiping Ye

et al.

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2024

2025

Publication Types

Select...

Article3

Relationship

Self Cite0

Independent3

Authors

Journals

Cited by 3 publications

References 51 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

Improving Oxygen‐Redox‐Active Layered Oxide Cathodes for Sodium‐Ion Batteries Through Crystal Facet Modulation and Fluorinated Interfacial Engineering

Sun,

Weng,

Zhou

et al. 2024

Advanced Materials

View full text Add to dashboard Cite

Layered oxides with active oxygen redox are attractive cathode materials for sodium‐ion batteries (SIBs) due to high capacity but suffer from rapid capacity/voltage deterioration and sluggish reaction kinetics stemming from lattice oxygen release, interfacial side reactions, and structural reconstruction. Herein, a synergistic strategy of crystal‐facet modulation and fluorinated interfacial engineering is proposed to achieve high capacity, superior rate capability, and long cycle stability in Na0.67Li0.24Mn0.76O2. The synthesized single‐crystal Na0.67Li0.24Mn0.76O2 (NLMO{010}) featuring increased {010} active facet exposure exhibits faster anionic redox kinetics and delivers a high capacity (272.4 mAh g−1 at 10 mA g−1) with superior energy density (713.9 Wh kg−1) and rate performance (116.4 mAh g−1 at 1 A g−1). Moreover, by incorporating N‐Fluorobenzenesulfonimide (NFBS) as electrolyte additive, the NLMO{010} cathode retains 84.6% capacity after 400 cycles at 500 mA g−1 with alleviated voltage fade (0.27 mV per cycle). Combined in situ analysis and theoretical calculations unveil dual functionality of NFBS, which results in thin yet durable fluorinated interfaces on the NLMO{010} cathode and hard carbon anode and scavenges highly reactive oxygen species. The results indicate the importance of fast‐ion‐transfer facet engineering and fluorinated electrolyte formulation to enhance oxygen redox‐active cathode materials for high‐energy‐density SIBs.

show abstract

Improving Oxygen‐Redox‐Active Layered Oxide Cathodes for Sodium‐Ion Batteries Through Crystal Facet Modulation and Fluorinated Interfacial Engineering

Sun,

Weng,

Zhou

et al. 2024

Advanced Materials

View full text Add to dashboard Cite

show abstract

Advanced Electrolyte Systems with Sultones Additives for High‐Voltage Lithium Batteries

Wan,

Zhong,

Liu

et al. 2024

Batteries & Supercaps

View full text Add to dashboard Cite

The new energy market is growing rapidly, lithium batteries (LBs) as the most important source of energy supply in the energy storage and power market, has higher requirements for fast charge and long life, so it is necessary to improve the cell voltage and energy density of LBs. However, LBs with high voltage and high energy density will face serious challenges of electrolyte decomposition and electrode corrosion in high voltage environment. Herein, this review summarizes the effects of a series of sultones as electrolyte additives in high voltage electrolytes. It is found that DTD, ES, 1,3‐PS, PES, PCS, MMDS, BDTD, BDTT, DTDph, ODTO, FPS, VES and other sultones have excellent properties on stabilizing SEI/CEI formation, inhibiting gas production, and good high temperature resistance. The preferential oxidation/reduction of sultones can protect the electrolyte from decomposition, and the uniform and dense SEI/CEI can also promote Li+ transport, protect the electrode from corrosion, prevent the growth of lithium dendrites, and promote the insertion and removal of Li+, so as to improve the cycle life of the high‐voltage battery. Therefore, sultones are very suitable as high‐voltage LBs electrolyte additives to improve the performance of cells. This review can provide theoretical support for the design of high voltage and high energy density LBs electrolyte and selection of additives in the future.

show abstract

An electrolyte design strategy for commercial all-climate pouch sodium-ion batteries

Li,

Liu,

Qiu

et al. 2025

Chemical Engineering Journal

View full text Add to dashboard Cite

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Novel sulfur-based electrolyte additive for constructing high-quality sulfur-containing electrode-electrolyte interphase films in sodium-ion batteries

Cited by 3 publications

References 51 publications

Improving Oxygen‐Redox‐Active Layered Oxide Cathodes for Sodium‐Ion Batteries Through Crystal Facet Modulation and Fluorinated Interfacial Engineering

Improving Oxygen‐Redox‐Active Layered Oxide Cathodes for Sodium‐Ion Batteries Through Crystal Facet Modulation and Fluorinated Interfacial Engineering

Advanced Electrolyte Systems with Sultones Additives for High‐Voltage Lithium Batteries

An electrolyte design strategy for commercial all-climate pouch sodium-ion batteries

Contact Info

Product

Resources

About