Analytical solutions of an unsteady magnetohydrodynamic (MHD) flow with heat and mass transfer characteristics of an incompressible, viscous, electrically conducting, and Boussinesq fluid over a vertical oscillating plate embedded in a Darcian porous medium in the presence of a thermal radiation are presented. The fluid considered here is a gray, absorbing/emitting radiating, but nonscattering medium. At time t > 0, the plate temperature and concentration near the plate are raised linearly with time t. The dimensionless governing coupled unsteady boundary layer partial differential equations are solved by the Laplace transform technique. An increase in permeability parameter (K) is found to increase fluid velocities and shear stress in the regime. Also it was found that when the conduction-radiation parameter (R) increased, the fluid velocity and the temperature profiles decreased. Applications of the study are found in materials processing and solar energy collector systems.