Numerical simulation of waste tyres gasification

Abstract

Gasification is a thermochemical pathway used to convert carbonaceous feedstock into syngas (CO and H2) in a deprived oxygen environment. The process can accommodate conventional feedstock such as coal, discarded waste including plastics, rubber, and mixed waste owing to the high reactor temperature (1000 °C-1600 °C). Pyrolysis is another conversion pathway, yet it is more selective to the feedstock owing to the low process temperature (350 °C-550 °C). Discarded tyres can be subjected to pyrolysis, however, the yield involves the formation of intermediate radicals additional to unconverted char. Gasification, however, owing to the higher temperature and shorter residence time, is more opted to follow quasi-equilibrium and being predictive. In this work, tyre crumbs are subjected to two levels of gasification modelling, i.e. equilibrium zero dimension and reactive multi-dimensional flow. The objective is to investigate the effect of the amount of oxidising agent on the conversion of tyre granules and syngas composition in a small 20 kW cylindrical gasifier. Initially the chemical compositions of several tyre samples are measured following the ASTM procedures for proximate and ultimate analysis as well as the heating value. The measured data are used to carry out equilibrium-based and reactive flow gasification. The result shows that both models are reasonably predictive averaging 50% gasification efficiency, the devolatilisation is less sensitive than the char conversion to the equivalence ratio as devolatilisation is always complete. In view of the high attained efficiency, it is suggested that the investigated tyre gasification system is economically viable.

Waste Rubber Pyrolysis: Product Yields and Limonene Concentration

“…Rubber waste can also be reclaimed as material in the form of fillers, granulates, or additives used for tire re-production [ 5 ]. The high calorific value of these materials provides the possibility for recovery of energy by gasification and combustion [ 6 ]. Usage of alternative energy sources, as well as different types of recycling, becomes a significant element of the product life-cycle.…”

Towards a Structured Framework for Techno‐Economic Analyses of Chemical Recycling Technologies

“…Generally, CR can be classified under four technological routes, namely solvent-based purification, depolymerization, liquefaction, and gasification, which, inter alia, differ in terms of their main recycling products [1,[32][33][34][35][36][37]:…”

Multi-Scale Modeling of Plastic Waste Gasification: Opportunities and Challenges

“…In Section 7, the multi-phase flow modeling in the reactor scale using the engineering or computational fluid dynamics (CFD) approaches is assessed. To the best of the authors' knowledge, few studies are focusing specifically on modeling the PWG process at different scales [29,[56][57][58][59][60][61][62][63][64][65]. The analysis that is made during the next sections is used to provide conclusions to bring the first principles-based multi-scale modeling of PWG a step closer.…”