Octahedral Chalcogenide Rhenium Clusters: From Solids to Isolated Cluster Complexes

A reaction between ReI 3 and KCN at elevated temperature led to the formation of the new cyanometalate cluster anion [{Re 4 (μ 3 -CCN) 4 }(CN) 12 ] 8− (1). The anion contains μ 3 -CCN 3− ligands, which are stabilized by the coordination to the triangular faces of the tetrahedral {Re 4 } metallocluster in a μ 3 mode. The compound crystallized as a potassium salt, and its crystal structure was determined by single-crystal X-ray diffraction analysis. It was shown that μ 3 -CCN 3− ligands are ambidentate and can interact with transition-metal cations similarly to terminal CN groups, resulting in the polymer framework formation.

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Octahedral Chalcogenide Rhenium Clusters: From Solids to Isolated Cluster Complexes

Cited by 11 publications

References 139 publications

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Octahedral Chalcogenide Rhenium Clusters: From Solids to Isolated Cluster Complexes

Cited by 11 publications

References 139 publications

Neutral Chalcogenide Tungsten Cluster with Tris(2‐Cyanoethyl)phosphine

Neutral Chalcogenide Tungsten Cluster with Tris(2‐Cyanoethyl)phosphine

Synthesis, structure and characterizations of a series of frameworks constructed from octahedral rhenium(III) chalcocyanide clusters, copper(I) and organic units

The {Re4} Tetrahedral Cyanometalate Cluster Anion [{Re4(μ3-CCN)4}(CN)12]8– with Inner (μ3-CCN)3– Ligands and Its Features in Coordination of Cu2+ Cations

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The {Re₄} Tetrahedral Cyanometalate Cluster Anion [{Re₄(μ₃-CCN)₄}(CN)₁₂]^8– with Inner (μ₃-CCN)^3– Ligands and Its Features in Coordination of Cu²⁺ Cations