Abstract:Nonstoichiometric oxides form a new chapter in tailored materials. Founding and construction of thermodynamic functions related to solid (geologic, metallurgic) materials is traced showing interactions between Czech Professor F. Wald and Russians R.S. Kurnakov and D.S. Korzhinskiĭ and further developed by Czech P. Holba in the initial phase definition and related characterization of partially open systems. A gradual increase in thermodynamic concepts related to solidstate description is investigated in more de… Show more
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