With the deepening of the reform and development of higher education, many colleges and universities have taken the merger as an opportunity to promote the leap-forward development of their schools. Some colleges and universities that have not merged have also taken the newly-built campus as a new growth point to promote the rapid development of their schools. The library’s collection structure reflects a library’s document support ability, and the formation of the collection structure depends on the accumulation of document resources. Based on semantic web technology, this paper studies the construction of library literature resources. Among the institutions that choose to give priority to the development of library literature resources in the development strategy of main literature resources, the proportion of long-term preservation practice has reached 65.23%, compared with 57.42% of all other institutions. Due to the small number of samples, we cannot make a simple statistical inference, but it may reflect from the other side that the institutions that pay attention to digital resources are slightly more active in implementing preservation activities than other institutions. Based on the semantic web technology, the integrity and continuity of important documents and characteristic resources were kept and we paid attention to the collection of publications and academic documents related to our school. Under the double restriction of document resources guarantee, the acquisition behavior of guarantee systems at all levels will gradually strengthen self-control, actively establish the concept of coordination and sharing, and gradually move from randomness to standardization.