In this work, the comparison of different deterministic methodologies to characterize channel behavior in heterogeneous and composite scenarios is presented. These techniques combine a 3-D Ray Launching approach based on Geometrical Optics, with other approaches based on Geometrical Optics and Uniform Theory of Diffraction, and a full technique, which also includes a Diffusion Equation method based on the equation of transfer. A new methodology based on Geometrical Optics and Diffusion Equation is presented and validated when compared with real measurements, achieving accurate results. The proposed technique provides a computational time reduction of up to 90% with respect to the conventional Geometrical Optics with Uniform Theory of Diffraction and Diffusion Equation approach.