One- and two-dimensional materials containing vanadium oxide: structures and magnetic properties of Cu(dien)V2O6·H2O and Ni(dien)V2O6 (dien = diethylenetriamine) †

Hydrothermal synthesis and structural characterization of a new two-dimensional vanadium oxide complex: [Co(2,2-bipy)(H2O)(VO3)2]

“…A least-square fit shows the parameters of g ¼ 2:12, J ¼ À0:82 cm À1 and F ¼ 0:397%. The small J value is comparable to those observed in [Cu(prn) 2 (VO 3 ) 2 ] [16] and [Cu(dien) (VO 3 ) 2 ] [18], where only very weak antiferromagnetic interactions occur between the magnetic centers.…”

Synthesis, Structure Characterization, and Quantum Chemistry of a Discrete Cluster [{Zn(2,2′-bipy)3}2V4O12]·11H2O (2,2′-bipy=2,2′-bipyridine)

“…In so-called "metavanadate" aqueous solution (pH. ca 6.5-8), the major components are the cyclic tetramer [V 4 O 12 ] (2) 1.794 (2) 111.08 (10) 135.20 (13) 109.14(12) 155.68 (14) (Zheng et al, 1999). 9 ¼ Cu(dien)V 2 O 6 (Zheng et al, 1999) 10 ¼ [V IV V V 2 O 7 (phen)] n (Duan et al, 1995).…”

An Interesting Array of Cyclic Tetramer Water in the Molecular Structure of [V6O12(phen)4(CH3O)4] · 4H2O

“…To our knowledge, most vanadium clusters are inorganic ligands that coordinate with another metal to produce the organic-inorganic hybrid materials, such as Cu(dien)V 2 O 6 . H 2 O [7] [(2,2-biphen)Co]V 3 O 8.5 [8] [Ni(en) 2 ] 0.5 [V 3 O 7 ] [9] [fZn(2,2-bipy) 3 g 2 V 4 O 12 ] . 11H 2 O, [10] [fCo(phen) 2 g 2 V 6 O 17 ] n , [11] [Ni(enMe)] 0.5 [H 2 enMe] 0.5 [V 6 O 14 ], [9] Cd[C 3 N 2 H 11 ] 2 [V 8 O 20 ], [12] [(2,2-Py 2 NH) 2 Co] 3 V 8 O 23 ] [13] and [fCu(phen) 2 g 4 V 10 O 29 ] .…”