One-pot syntheses, structures and properties of two novel 1-D copper complexes: [CuII2(Hbpdc)2Cl2]2·2H2O and CuI(H2bpdc)Cl (H2bpdc = 2,2′-bipyridyl-5,5′-dicarboxylic acid)

An organic–inorganic hybrid dimeric arsenotungstate [enH2]4{[Cu(en)2][(A-β-H2AsW9O34)Cu(en)2]2}·8H2O established by two trivacant Keggin [A-β-AsW9O34]9− fragments in the opposite orientation

“…These results suggested that the Er III ion played a synergistic action with other components in the formation of 1 although its specific role was not well understood in the reaction. Similar phenomena have been previously encountered [32,33]. Currently, we are changing the usage amount of ErCl 3 or making use of other Ln cations in place of the Er III cation to synthesize new 3d-4f heterometallic AT analogs.…”

Di-μ-chlorido-bis[(2,2′-bipyridine-5,5′-dicarboxylic acid-κ2N,N′)chloridocopper(II)] dimethylformamide tetrasolvate

“…3). A polymeric copper(II) complex with the same organoligand as in (I) but with a Cu/Cl ratio of 1:1 has been reported by Zhao et al (2010).…”

“…For related structures with similar coordination geometry around the copper atoms, see: Goddard et al (1990); Tynan et al (2005); Han et al (2008); Liu et al (2009); Qi et al (2009). For other related structures of chloro bipyridine copper complexes, see: Wang et al (2004); Zhao et al (2010). = 68.332 (6) V = 1069.4 (11) Å 3 Z = 1 Mo K radiation = 1.32 mm À1 T = 100 K 0.20 Â 0.15 Â 0.02 mm…”

Poly[[diaqua(μ4-benzene-1,2,4,5-tetracarboxylato)tetrakis(1H-imidazole-κN3)dicopper(II)]N,N-dimethylformamide monosolvate]

“…For related structures, see: Zhan & Li (2010); Luo et al (2007); Yang et al (2004). For the synthesis, see: Zhao et al (2010). Selected bond lengths (Å ).…”

“…A dimethylformamide (DMF) solution (20 ml) of benzene-1,2,4,5-tetracarboxylic acid (0.1 mmol,0.0254 g) was added dropwise to an aqueous solution (10 ml) containing copper sulfate pentahydrate (0.2 mmol,0.0498 g), N,N-carbonyldiimidazole (0.3 mmol,0.0486 g) and NaOH (0.01 mmol, 0.0004 g) at room temperature (Zhao et al, 2010). The reaction mixture was filtered and the filtrate was left to stand for about three weeks until blue single crystals were obtained (yield 31%, based on Cu).…”