One-pot three-step mechanically assisted synthesis and catalytic performance of tripodal metallic complexes

Tedjini, Rima; Viveiros, Raquel; Casimiro, Teresa; Bonifácio, Vasco D. B.

doi:10.1039/d1re00194a

Cited by 4 publications

(2 citation statements)

References 21 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Owing to the existence of two stereogenic centers in the structure, dihydrocarvone has four stereoisomers, namely, (2 R ,5 R ), (2 R ,5 S ), (2 S ,5 R ), and (2 S ,5 S ) (Figure ). In previous studies, metal catalysis, − acid catalysis, − and electrooxidation synthesized dihydrocarvone starting from carvone or limonene without considering the stereoselectivity of the product.…”

Section: Terpenoid Flavormentioning

confidence: 99%

Applications of Ene-Reductases in the Synthesis of Flavors and Fragrances

Fan,

Yu,

Yao

et al. 2024

J. Agric. Food Chem.

View full text Add to dashboard Cite

Flavors and fragrances (F&F) are interesting organic compounds in chemistry. These compounds are widely used in the food, cosmetic, and medical industries. Enzymatic synthesis exhibits several advantages over natural extraction and chemical preparation, including a high yield, stable quality, mildness, and environmental friendliness. To date, many oxidoreductases and hydrolases have been used to biosynthesize F&F. Ene-reductases (ERs) are a class of biocatalysts that can catalyze the asymmetric reduction of α,β-unsaturated compounds and offer superior specificity and selectivity; therefore, ERs have been increasingly considered an ideal alternative to their chemical counterparts. This review summarizes the research progress on the use of ERs in F&F synthesis over the past 20 years, including the achievements of various scholars, the differences and similarities among the findings, and the discussions of future research trends related to ERs. We hope this review can inspire researchers to promote the development of biotechnology in the F&F industry.

show abstract

Section: Terpenoid Flavormentioning

confidence: 99%

Applications of Ene-Reductases in the Synthesis of Flavors and Fragrances

Fan,

Yu,

Yao

et al. 2024

J. Agric. Food Chem.

View full text Add to dashboard Cite

show abstract

“…The former adds to this growing body of mechanochemically prepared coordination complexes, and the latter demonstrates the feasibility of increasingly complex one-pot reaction systems via mechanochemistry, with notable prior examples from Friščić, Lamaty, James, Hanusa, Garcia, and others. 24–48…”

Section: Introductionmentioning

confidence: 99%