Optimization and kinetic study of biodiesel production from Jatropha curcas oil in supercritical methanol environment using ZnO/γ-Al2O3 catalyst

Abstract

In this study, the conversion of crude Jatropha curcas oil into biodiesel through transesterification was investigated in the presence of heterogeneous solid catalysts under supercritical methanol environment. The principal impetuses catalyzing the expansion in optimal biodiesel production are primarily attributed to the increasing demand for sustainable energy sources, the availability of raw materials, and innovations in production methodologies. To maintain the optimization, 6 wt% and 10 wt% of zinc oxide (ZnO) were incorporated into gamma-alumina (γ-Al2O3) through a wet impregnation method followed by calcination at 900 °C. Furthermore, the study examined the effect of alcohol/oil molar ratio, reaction temperature, and reaction time on the process to achieve maximum biodiesel production. The study revealed that a catalyst consisting of 10 wt% ZnO on γ-Al2O3 exhibited exceptional performance with a biodiesel yield of 95.64% under the reaction conditions of a molar ratio of 1:40 oil to methanol, a temperature of 300 °C, a pressure of 9 MPa, and a residence time of 3 min compared to the yield of 100% under same condition at residence time of 9 min. After thorough investigation, the kinetics of the catalytic transesterification reaction were elucidated, and suitable kinetic parameters were proposed.