Optimization of performance and sensitivity: preparation of two Ag(i)-based ECPs by using isomeric ligands

Abstract

For energetic compounds, structure determines performance, and even minor variations of structure can have a significant impact on performance. The application scenarios for energetic materials are diverse, and their performance...

A novel energetic pyridine-2-carbohydrazide copper perchlorate complex: synthesis, cationic ligand structure and properties

“…Zhang et al have synthesized a series of hydrazide-based copper perchlorate and silver perchlorate complexes in the past few decades. 21–24 Although most of reported ECCs had good detonation properties and simple synthesis method, their ECCs were really sensitive to external stimuli. The operation risks cannot be ignored.…”

N^N^C-Cyclometalated rhodium(iii) complexes with isomeric pyrimidine-based ligands: unveiling the impact of isomerism on structural motifs, luminescence and cytotoxicity

“…Despite various kinds of constitutional and configurational isomerism of metal complexes being well known, 40 ligand isomerism, which belongs to constitutional isomerism, is documented in literature to a considerably lesser extent than other types of the isomerism of complexes. 23,41–64…”